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Source values are parenthesized where unit conversions were performed. M denotes the non-SI unit molar: 1 M = 1 mol/L = 10 −3 mol/m 3. ... (12 800 ppm) [15] 10 −3: mM
In the International System of Units (SI), the coherent unit for molar concentration is mol/m 3. However, most chemical literature traditionally uses mol/dm 3, which is the same as mol/L. This traditional unit is often called a molar and denoted by the letter M, for example: 1 mol/m 3 = 10 −3 mol/dm 3 = 10 −3 mol/L = 10 −3 M = 1 mM = 1 ...
Atmospheric pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m 3, μg/m 3, etc.) at sea level will decrease with increasing altitude because the atmospheric pressure decreases with increasing altitude. The change of atmospheric pressure with altitude can be obtained from this equation: [2]
1 J·m 3 /mol 2 = 1 m 6 ·Pa/mol 2 = 10 L 2 ·bar/mol 2. 1 L 2 atm/mol 2 = 0.101325 J·m 3 /mol 2 = 0.101325 Pa·m 6 /mol 2. 1 dm 3 /mol = 1 L/mol = 1 m 3 /kmol = 0.001 m 3 /mol (where kmol is kilomoles = 1000 moles)
The molar concentration is defined as the amount of a constituent (in moles) divided by the volume of the mixture : =. The SI unit is mol/m 3. However, more commonly the unit mol/L (= mol/dm 3) is used.
mg/m 3 = milligrams of pollutant per cubic meter of air at sea level atmospheric pressure and T: ppmv = air pollutant concentration, in parts per million by volume T = ambient temperature in K = 273. + °C 0.082057338 = Universal gas constant in L atm mol −1 K −1: M = molecular mass (or molecular weight) of the air pollutant
For example, the conversion factor between a mass fraction of 1 ppb and a mole fraction of 1 ppb is about 4.7 for the greenhouse gas CFC-11 in air (Molar mass of CFC-11 / Mean molar mass of air = 137.368 / 28.97 = 4.74). For volume fraction, the suffix "V" or "v" is sometimes appended to the parts-per notation (e.g. ppmV, ppbv, pptv).
The concentrations of standard solutions are normally expressed in units of moles per litre (mol/L, often abbreviated to M for molarity), moles per cubic decimetre (mol/dm 3), kilomoles per cubic metre (kmol/m 3), grams per milliliters (g/mL), or in terms related to those used in particular titrations (such as titres).