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Chemical water analysis is carried out on water used in industrial processes, on waste-water stream, on rivers and stream, on rainfall and on the sea. [1] In all cases the results of the analysis provides information that can be used to make decisions or to provide re-assurance that conditions are as expected.
The second part of the Winkler test reduces (acidifies) the solution. The precipitate will dissolve back into solution as the H + reacts with the O 2− and OH − to form water. MnO(OH) 2 (s) + 4 H + (aq) → Mn 4+ (aq) + 3 H 2 O(l) The acid facilitates the conversion by the brown, Manganese-containing precipitate of the Iodide ion into ...
Gravimetric analysis describes a set of methods used in analytical chemistry for the quantitative determination of an analyte (the ion being analyzed) based on its mass. The principle of this type of analysis is that once an ion's mass has been determined as a unique compound, that known measurement can then be used to determine the same analyte's mass in a mixture, as long as the relative ...
For example, FeSO 4 is named iron(2+) sulfate (with the 2+ charge on the Fe 2+ ions balancing the 2− charge on the sulfate ion), whereas Fe 2 (SO 4) 3 is named iron(3+) sulfate (because the two iron ions in each formula unit each have a charge of 3+, to balance the 2− on each of the three sulfate ions). [108]
This includes ions which form sulfides that are insoluble at high concentrations. The reagents used are H 2 S in the presence of NH 4 OH. NH 4 OH is used to increase the concentration of the sulfide ion, by the common ion effect - hydroxide ions from NH 4 OH combine with H + ions from H 2 S, which shifts the equilibrium in favor of the ionized ...
This is a common laboratory test to determine if sulfate anions are present. The sulfate ion can act as a ligand attaching either by one oxygen (monodentate) or by two oxygens as either a chelate or a bridge. [7] An example is the complex Co 2 (SO 4)] + Br − [7] or the neutral metal complex PtSO 4 (PPh 3) 2] where the sulfate ion is acting as ...
To identify the cation, the color of the precipitate and its solubility in excess are noted. Similar processes are often used in sequence – for example, a barium nitrate solution will react with sulfate ions to form a solid barium sulfate precipitate, indicating that it is likely that sulfate ions are present.
The net reaction between an aldehyde (or an alpha-hydroxy-ketone) and the copper(II) ions in Benedict's solution may be written as: RCHO + 2 Cu 2+ + 5 OH − → RCOO − + Cu 2 O + 3 H 2 O. The hydroxide ions in the equation forms when sodium carbonate dissolves in water. With the citrate included, the reaction becomes: