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Tungsten hexafluoride was first obtained by conversion of tungsten hexachloride with hydrogen fluoride by Otto Ruff and Fritz Eisner in 1905. [11] [12] WCl 6 + 6 HF → WF 6 + 6 HCl. The compound is now commonly produced by the exothermic reaction of fluorine gas with tungsten powder at a temperature between 350 and 400 °C: [7] W + 3 F 2 → WF 6
The direct reaction of hydrocarbons with fluorine gas can be dangerously reactive, so the temperature may need to be lowered even to −150 °C (−240 °F). [115] " Solid fluorine carriers", compounds that can release fluorine upon heating, notably cobalt trifluoride , [ 116 ] may be used instead, or hydrogen fluoride.
The speed of sound in any chemical element in the fluid phase has one temperature-dependent value. In the solid phase, different types of sound wave may be propagated, each with its own speed: among these types of wave are longitudinal (as in fluids), transversal, and (along a surface or plate) extensional.
Tungsten hexafluoride is not a gas at standard conditions. STP for gases is defined as 0° C and 1 atm. The standard boiling point of this compound is listed as 17.1° C. It is a gas at room temperature, but not at standard temperature. 144.162.23.122 22:27, 24 September 2013 (UTC) Good point.
(i) Indicates values calculated from ideal gas thermodynamic functions. (s) Indicates the substance is solid at this temperature. As quoted from these sources: a - Lide, D.R., and Kehiaian, H.V., CRC Handbook of Thermophysical and Thermochemical Data, CRC Press, Boca Raton, Florida, 1994.
Boca Raton, Florida, 2003; Section 6, Fluid Properties; Critical Constants. Also agrees with Celsius values from Section 4: Properties of the Elements and Inorganic Compounds, Melting, Boiling, Triple, and Critical Point Temperatures of the Elements Estimated accuracy for Tc and Pc is indicated by the number of digits.
Tungsten hexafluoride (tungsten(VI) fluoride) This page was last edited on 18 July 2023, at ...
This is a list of gases at standard conditions, ... Tungsten hexafluoride: WF 6: 17.1 1.9 294 ... Methanetellurol CH 3 TeH 25284-83-7 unstable at room temperature.