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Diamond and graphite are two allotropes of carbon: pure forms of the same element that differ in crystalline structure.. Allotropy or allotropism (from Ancient Greek ἄλλος (allos) 'other' and τρόπος (tropos) 'manner, form') is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements.
Phagraphene: Graphene-like allotrope with distorted Dirac cones. Prismane C 8 is a theoretically predicted metastable carbon allotrope comprising an atomic cluster of eight carbon atoms, with the shape of an elongated triangular bipyramid—a six-atom triangular prism with two more atoms above and below its bases. [45]
The diphosphorus allotrope (P 2) can normally be obtained only under extreme conditions (for example, from P 4 at 1100 kelvin). In 2006, the diatomic molecule was generated in homogeneous solution under normal conditions with the use of transition metal complexes (for example, tungsten and niobium ).
Triatomic oxygen (ozone, O 3) is a very reactive allotrope of oxygen that is a pale blue gas at standard temperature and pressure. Liquid and solid O 3 have a deeper blue color than ordinary O 2, and they are unstable and explosive. [5] [6] In its gas phase, ozone is destructive to materials like rubber and fabric and is damaging to lung tissue ...
These allotropes have been synthesised by various methods for example, treating titanocene pentasulfide and a dichlorosulfane of suitable sulfur chain length, S n−5 Cl 2: [17] (η 5-C 5 H 5) 2 TiS 5 + S n−5 Cl 2 → cyclo-S n + (η 5-C 5 H 5) 2 TiCl 2. or alternatively treating a dichlorosulfane, S n−m Cl 2 and a polysulfane, H 2 S m: [17 ...
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Below 912 °C (1,674 °F), iron has a body-centered cubic (bcc) crystal structure and is known as α-iron or ferrite.It is thermodynamically stable and a fairly soft metal. α-Fe can be subjected to pressures up to ca. 15 GPa before transforming into a high-pressure form termed ε-Fe discussed below.
A fifth allotrope of carbon, discovered in 2003, is called graphene, and is in the form of a layer of carbon atoms arranged in a honeycomb-shaped formation. [6] [14] [15] Silicon has two known allotropes that exist at room temperature. These allotropes are known as the amorphous and the crystalline allotropes. The amorphous allotrope is a brown ...