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Radical elimination can be viewed as the reverse of radical addition. In radical elimination, an unstable radical compound breaks down into a spin-paired molecule and a new radical compound. Shown below is an example of a radical elimination reaction, where a benzoyloxy radical breaks down into a phenyl radical and a carbon dioxide molecule. [7]
In number theory, the radical of a positive integer n is defined as the product of the distinct prime numbers dividing n. Each prime factor of n occurs exactly once as a factor of this product: r a d ( n ) = ∏ p ∣ n p prime p {\displaystyle \displaystyle \mathrm {rad} (n)=\prod _{\scriptstyle p\mid n \atop p{\text{ prime}}}p}
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
The hydroxyl radical can damage virtually all types of macromolecules: carbohydrates, nucleic acids , lipids (lipid peroxidation) and amino acids (e.g. conversion of Phe to m-Tyrosine and o-Tyrosine). The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5]
As an example, the cyanide (CN) radical shown below is a type (a) radical that has ten bonding electrons, while the cyanogen molecule (a dimeric combination of two CN radicals) has 14 bonding electrons. (a) The top shows both the dot-and-cross diagram and the simplified diagram of the LDQ structure of the CN radical.
Every nonnegative real number x has a unique nonnegative square root, called the principal square root or simply the square root (with a definite article, see below), which is denoted by , where the symbol " " is called the radical sign [2] or radix. For example, to express the fact that the principal square root of 9 is 3, we write =.
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Both the negatively charged anion HO −, called hydroxide, and the neutral radical HO·, known as the hydroxyl radical, consist of an unbonded hydroxy group. According to IUPAC definitions, the term hydroxyl refers to the hydroxyl radical (·OH) only, while the functional group −OH is called a hydroxy group. [1]