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Orpiment, also known as ″yellow arsenic blende″ is a deep-colored, orange-yellow arsenic sulfide mineral with formula As 2 S 3.It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and may be formed through sublimation.
It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment (Latin: auripigmentum), which has been used as a pigment called King's yellow. It is produced in the analysis of arsenic compounds. It is a group V/VI, intrinsic p-type semiconductor and exhibits photo-induced phase-change properties. [clarification needed]
Arsenic blende or Arsenblende (German: Arsenblende, arsenik-blende) is a trivial name that has partially fallen out of scientific use, used by mineralogists, as well as representatives of mining and craft professions in relation to at least two similar ore minerals — orpiment and realgar, [1]: 135, 239, 438 in composition — arsenic sulfides.
Gypsum – a mineral; calcium sulfate. CaSO 4; Horn silver/argentum cornu – a weathered form of chlorargyrite, an ore of silver chloride. Luna cornea – silver chloride, formed by heating horn silver till it liquefies and then cooling. King's yellow – formed by mixing orpiment with white arsenic.
Realgar (/ r i ˈ æ l ɡ ɑːr,-ɡ ər / ree-AL-gar, -gər), also known as arsenic blende, ruby sulphur or ruby of arsenic, is an arsenic sulfide mineral with the chemical formula α-As 4 S 4. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related ...
Arsenic trisulfide, As 2 S 3, the mineral orpiment; Arsenic pentasulfide, As 2 S 5, similar structure to phosphorus pentasulfide (β-P 2 S 5) Tetraarsenic tetrasulfide, As 4 S 4 (2 isomers): the mineral realgar; the mineral pararealgar; Tetraarsenic trisulfide, As 4 S 3, the mineral α- or β- dimorphite
With 46% arsenic content, arsenopyrite, along with orpiment, is a principal ore of arsenic. When deposits of arsenopyrite become exposed to the atmosphere, the mineral slowly converts into iron arsenates. Arsenopyrite is generally an acid-consuming sulfide mineral, unlike iron pyrite which can lead to acid mine drainage. [citation needed]
Red Getchellite and yellow Orpiment from the Getchell Mine, the type locality.. Getchellite is a rare sulfide of arsenic and antimony, AsSbS 3, that was discovered by B. G. Weissberg of the New Zealand Department of Scientific and Industrial Research in 1963, and approved as a new species by the International Mineralogical Association in 1965.
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