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The copper coulometer is a one application for the copper-copper(II) sulfate electrode. [ 1 ] [ 2 ] Such a coulometer consists of two identical copper electrodes immersed in slightly acidic pH-buffered solution of copper(II) sulfate .
The copper–copper(II) sulfate electrode is a reference electrode of the first kind, [1] based on the redox reaction with participation of the metal and its salt, copper(II) sulfate. It is used for measuring electrode potential and is the most commonly used reference electrode for testing cathodic protection corrosion control systems. [ 2 ]
As quoted in an online version of: David R. Lide (ed), CRC Handbook of Chemistry and Physics, 84th Edition.CRC Press. Boca Raton, Florida, 2003; Section 4, Properties of the Elements and Inorganic Compounds; Physical Properties of the Rare Earth Metals
The overall chemical reaction taking place in a cell is made up of two independent half-reactions, which describe chemical changes at the two electrodes. To focus on the reaction at the working electrode , the reference electrode is standardized with constant (buffered or saturated) concentrations of each participant of the redox reaction.
Copper(II) sulfate is an inorganic compound with the chemical formula Cu SO 4.It forms hydrates CuSO 4 ·nH 2 O, where n can range from 1 to 7. The pentahydrate (n = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, [10] while its anhydrous form is white. [11]
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: . 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g). Metals in the middle of the reactivity series, such as iron, will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt, such as iron(II) sulfate:
This means that all pure copper (Cu) wires (which have not been subjected to distortion of their crystalline structure etc.), irrespective of their shape and size, have the same resistivity, but a long, thin copper wire has a much larger resistance than a thick, short copper wire. Every material has its own characteristic resistivity.
Simplified diagram of the Copper–Chlorine cycle. The copper–chlorine cycle (Cu–Cl cycle) is a four-step thermochemical cycle for the production of hydrogen. The Cu–Cl cycle is a hybrid process that employs both thermochemical and electrolysis steps. It has a maximum temperature requirement of about 530 degrees Celsius.