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Polystyrene sulfonic acid, the acid whose salts are the polystyrene sulfonates, has the idealized formula (CH 2 CHC 6 H 4 SO 3 H) n. The material is prepared by sulfonation of polystyrene: (CH 2 CHC 6 H 5) n + n SO 3 → (CH 2 CHC 6 H 4 SO 3 H) n. Several methods exist for this conversion, which can lead to varying degree of sulfonation.
Potassium binders are medications that bind potassium ions in the gastrointestinal tract, thereby preventing its intestinal absorption. This category formerly consisted solely of polystyrene sulfonate, a polyanionic resin attached to a cation, administered either orally or by retention enema to patients who are at risk of developing hyperkalaemia (abnormal high serum potassium levels).
Polystyrene integrated solid foams are not commonly used in biomedical applications but have shown promise as a new drug delivery vehicle. The manipulation of the porous foam networks is a fundamental component in solid foam dosing – affecting variables such as dissolution, adsorption, and drug diffusion. [4]
The original synthesis of PAES involved electrophilic aromatic substitution of an diaryl ether with the bis (sulfonyl chloride) of benzene. Reactions typically use a Friedel-Crafts catalyst, such as ferric chloride or antimony pentachloride: n O(C 6 H 5) 2 + n SO2Cl2 → {[O(C 6 H 4) 2]SO 2} n + 2n HCl
Poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) is a composite material where PEDOT (the conductive polymer) provides electrical conductivity, and PSS (polystyrene sulfonate) acts as a counter-ion to balance the charge and improve the water solubility and processability of PEDOT.
Lignosulfonates (LS) are water-soluble anionic polyelectrolyte polymers: they are byproducts from the production of wood pulp using sulfite pulping. [1] Most delignification in sulfite pulping involves acidic cleavage of ether bonds, which connect many of the constituents of lignin. [2]
Many method have been developed for introducing sulfonate groups aside from direction sulfonation. A classic named reaction is the Piria reaction (Raffaele Piria, 1851) in which nitrobenzene is treated with a metal bisulfite forming an aminosulfonic acid as a result of combined nitro group reduction and sulfonation. [2] [5] [6] The Piria reaction
The sulfonate ion. In organosulfur chemistry, a sulfonate is a salt, anion or ester of a sulfonic acid. Its formula is R−S(=O) 2 −O −, containing the functional group −S(=O) 2 −O −, where R is typically an organyl group, amino group or a halogen atom. Sulfonates are the conjugate bases of sulfonic acids.