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Polyatomic ions often are useful in the context of acid–base chemistry and in the formation of salts. Often, a polyatomic ion can be considered as the conjugate acid or base of a neutral molecule. For example, the conjugate base of sulfuric acid (H 2 SO 4) is the polyatomic hydrogen sulfate anion (HSO − 4).
The phosphotungstate anion, an example of a polyoxometalate. In chemistry, a polyoxometalate (abbreviated POM) is a polyatomic ion, usually an anion, that consists of three or more transition metal oxyanions linked together by shared oxygen atoms to form closed 3-dimensional frameworks.
Functional groups can also be charged, e.g. in carboxylate salts (−COO −), which turns the molecule into a polyatomic ion or a complex ion. Functional groups binding to a central atom in a coordination complex are called ligands. Complexation and solvation are also caused by specific interactions of functional groups.
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [5]
In chemistry, isomers are molecules or polyatomic ions with identical molecular formula – that is, the same number of atoms of each element – but distinct arrangements of atoms in space. [1] Isomerism refers to the existence or possibility of isomers. Isomers do not necessarily share similar chemical or physical properties.
Quaternary ammonium cation. The R groups may be the same or different alkyl or aryl groups. Also, the R groups may be connected. In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure [NR 4] +, where R is an alkyl group, an aryl group [1] or organyl group.
The explanation for the behavior is complicated, having to do with various cluster-forming tendencies of HF, water, and fluoride ion, as well as thermodynamic issues. [note 3] At great concentrations, a property called homoconjugation is revealed. HF begins to accept fluoride ions, forming the polyatomic ions (such as bifluoride, HF −
The phosphite ion, PO 3− 3, is a strong base, and so always carries at least one proton. In this case the proton is attached directly to the phosphorus atom with the structure HPO 2− 3. In forming this ion, the phosphite ion is behaving as a Lewis base and donating a pair of electrons to the Lewis acid, H +. Predominance diagram for chromate