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Buffer capacity falls to 33% of the maximum value at pH = pK a ± 1, to 10% at pH = pK a ± 1.5 and to 1% at pH = pK a ± 2. For this reason the most useful range is approximately pK a ± 1. When choosing a buffer for use at a specific pH, it should have a pK a value as close as possible to that pH. [2]
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.
Acid-neutralizing capacity or ANC in short is a measure for the overall buffering capacity against acidification of a solution, e.g. surface water or soil water.. ANC is defined as the difference between cations of strong bases and anions of strong acids (see below), or dynamically as the amount of acid needed to change the pH value from the sample's value to a chosen different value. [1]
The buffering capacity of a soil depends on the clay content of the soil, the type of clay, and the amount of organic matter present, and may be related to the soil cation exchange capacity. Soils with high clay content will have a higher buffering capacity than soils with little clay, and soils with high organic matter will have a higher ...
'ashes of the saltwort') [1] is the capacity of water to resist acidification. [2] It should not be confused with basicity, which is an absolute measurement on the pH scale. Alkalinity is the strength of a buffer solution composed of weak acids and their conjugate bases.
Effect of soil pH on cation-exchange capacity. The amount of negative charge from deprotonation of clay hydroxy groups or organic matter depends on the pH of the surrounding solution. Increasing the pH (i.e. decreasing the concentration of H + cations) increases this variable charge, and therefore also increases the cation-exchange capacity.
Soil acidification is the buildup of hydrogen cations, which reduces the soil pH. Chemically, this happens when a proton donor gets added to the soil. The donor can be an acid, such as nitric acid, sulfuric acid, or carbonic acid. It can also be a compound such as aluminium sulfate, which reacts in the soil to release protons.
In the past it could take years to publish a paper soil survey. Today it takes only moments for changes to go live to the public. The most current soil survey data is made available for high end GIS users such as professional consulting companies and universities. Typical information in a published county soil survey includes the following: [1]