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It was originally defined so that the specific heat capacity of liquid water would be 1 cal/(°C⋅g). The grand calorie (kilocalorie, kilogram-calorie, food calorie, kcal, Cal) is 1000 small calories, 4184 J exactly. It was defined so that the specific heat capacity of water would be 1 Cal/(°C⋅kg).
Table of specific heat capacities at 25 °C (298 K) unless otherwise noted. [citation needed] Notable minima and maxima are shown in maroon. Substance Phase Isobaric mass heat capacity c P J⋅g −1 ⋅K −1 Molar heat capacity, C P,m and C V,m J⋅mol −1 ⋅K −1 Isobaric volumetric heat capacity C P,v J⋅cm −3 ⋅K −1 Isochoric ...
In those contexts, the unit of heat capacity is 1 BTU/°R ≈ 1900 J/K. [5] The BTU was in fact defined so that the average heat capacity of one pound of water would be 1 BTU/°F. In this regard, with respect to mass, note conversion of 1 Btu/lb⋅°R ≈ 4,187 J/kg⋅K [ 6 ] and the calorie (below).
Water has a very high specific heat capacity of 4184 J/(kg·K) at 20 °C (4182 J/(kg·K) at 25 °C)—the second-highest among all the heteroatomic species (after ammonia), as well as a high heat of vaporization (40.65 kJ/mol or 2268 kJ/kg at the normal boiling point), both of which are a result of the extensive hydrogen bonding between its ...
The centigrade heat unit (CHU) is the amount of heat required to raise the temperature of one pound (0.45 kg) of water by one Celsius degree. It is equal to 1.8 Btu or 1,899 joules. [26] In 1974, this unit was "still sometimes used" in the United Kingdom as an alternative to Btu. [27]
The proportionality factor is the specific heat capacity, which depends on the nature of the substance, but which was not described until some time after Richmann's discovery by Joseph Black. Thus, the validity of the formula is limited to mixtures of the same substance, since it assumes a uniform specific heat capacity. [9]
The SI unit of volumetric heat capacity is joule per kelvin per cubic meter, J⋅K −1 ⋅m −3. The volumetric heat capacity can also be expressed as the specific heat capacity (heat capacity per unit of mass, in J⋅K −1 ⋅kg −1) times the density of the substance (in kg/L, or g/mL). [1] It is defined to serve as an intensive property.
Data in the table above is given for water–steam equilibria at various temperatures over the entire temperature range at which liquid water can exist. Pressure of the equilibrium is given in the second column in kPa. The third column is the heat content of each gram of the liquid phase relative to water at 0 °C.