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Heyrovský's Polarograph. Polarography is an electrochemical voltammetric technique that employs (dropping or static) mercury drop as a working electrode. In its most simple form polarography can be used to determine concentrations of electroactive species in liquids by measuring their mass-transport limiting currents.
Galvanic corrosion is the electrochemical erosion of metals. Corrosion occurs when two dissimilar metals are in contact with each other in the presence of an electrolyte, such as salt water. This forms a galvanic cell, with hydrogen gas forming on the more noble (less active) metal.
Workplace with Polarograph on the left. A Polarograph is a chemical analysis instrument used to record automatic voltage-intensity curves.. The Polarograph uses an electrolytic cell consisting of an electrode or microelectrode small area, generally of the mercury drop type, which is a very fine capillary tube through which mercury flows slowly, which comes in the form of small droplets, which ...
The reference is the most complex of the three electrodes; there are a variety of standards used. For non-aqueous work, IUPAC recommends the use of the ferrocene/ferrocenium couple as an internal standard. [8] In most voltammetry experiments, a bulk electrolyte (also known as a supporting electrolyte) is used to minimize solution resistance. It ...
The galvanic series (or electropotential series) determines the nobility of metals and semi-metals. When two metals are submerged in an electrolyte, while also electrically connected by some external conductor, the less noble (base) will experience galvanic corrosion. The rate of corrosion is determined by the electrolyte, the difference in ...
Most electrodes work over a limited range of conditions, such as pH or temperature, outside of this range the electrodes behavior becomes unpredictable. The advantage of a pseudo-reference electrode is that the resulting variation is factored into the system allowing researchers to accurately study systems over a wide range of conditions.
Galvanic isolation is a principle of isolating functional sections of electrical systems to prevent current flow; no direct conduction path is permitted. [ 1 ] [ 2 ] Energy or information can still be exchanged between the sections by other means, such as capacitive , inductive , radiative , optical , acoustic , or mechanical coupling.
Potentiometric Probes, LLC specializes only in voltage sensitive dyes; they have an exclusive license to distribute the large set of fluorinated VSDs, marketed under the ElectroFluor brand. A variety of specialized equipment may be used in conjunction with the dyes, and choices in equipment will vary according to the particularities of a ...