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In lay terms, the stoichiometric coefficient of any given component is the number of molecules and/or formula units that participate in the reaction as written. A related concept is the stoichiometric number (using IUPAC nomenclature), wherein the stoichiometric coefficient is multiplied by +1 for all products and by −1 for all reactants.
Partition coefficient (K D) - The ratio of concentrations of a compound in two phases of a mixture of two immiscible solvents at equilibrium. Hall coefficient (electrical physics) - Relates a magnetic field applied to an element to the voltage created, the amount of current and the element thickness. It is a characteristic of the material from ...
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
The generalisation of the law of mass action, in terms of affinity, to equilibria of arbitrary stoichiometry was a bold and correct conjecture. The hypothesis that reaction rate is proportional to reactant concentrations is, strictly speaking, only true for elementary reactions (reactions with a single mechanistic step), but the empirical rate ...
[1] [2] At chemical equilibrium or in phase equilibrium, the total sum of the product of chemical potentials and stoichiometric coefficients is zero, as the free energy is at a minimum. [3] [4] [5] In a system in diffusion equilibrium, the chemical potential of any chemical species is uniformly the same everywhere throughout the system. [6]
Some authors [5] [6] include the free reactant terms in the sums by declaring identity (unit) β constants for which the stoichiometric coefficients are 1 for the reactant concerned and zero for all other reactants. For example, with 2 reagents, the mass-balance equations assume the simpler form.
n j are the stoichiometric coefficients of the reactants in the equilibrium equation, and m j are the coefficients of the products. The value of δG r for these reactions is a function of the chemical potentials of all the species.
In the above, we note that the stoichiometric number of a reactant is negative. Now when we know the extent, we can rearrange the equation and calculate the equilibrium amounts of B and C. n e q u i , i = ξ e q u i ν i + n i n i t i a l , i {\displaystyle n_{equi,i}=\xi _{equi}\nu _{i}+n_{initial,i}}