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Hammond's postulate (or alternatively the Hammond–Leffler postulate), is a hypothesis in physical organic chemistry which describes the geometric structure of the transition state in an organic chemical reaction. [1] First proposed by George Hammond in 1955, the postulate states that: [2]
In chemistry, sigma hole interactions (or σ-hole interactions) are a family of intermolecular forces that can occur between several classes of molecules and arise from an energetically stabilizing interaction between a positively-charged site, termed a sigma hole, and a negatively-charged site, typically a lone pair, on different atoms that are not covalently bonded to each other. [1]
The 2014 AP Chemistry exam was the first administration of a redesigned test as a result of a redesigning of the AP Chemistry course. The exam format is now different from the previous years, with 60 multiple choice questions (now with only four answer choices per question), 3 long free response questions, and 4 short free response questions.
In chemistry, transition state theory (TST) explains the reaction rates of elementary chemical reactions. The theory assumes a special type of chemical equilibrium (quasi-equilibrium) between reactants and activated transition state complexes. [1] TST is used primarily to understand qualitatively how chemical reactions take place.
Directional statistics is the subdiscipline of statistics that deals with directions (unit vectors in R n), axes (lines through the origin in R n) or rotations in R n. The means and variances of directional quantities are all finite, so that the central limit theorem may be applied to the particular case of directional statistics.
In multivariable calculus, the directional derivative measures the rate at which a function changes in a particular direction at a given point. [citation needed]The directional derivative of a multivariable differentiable (scalar) function along a given vector v at a given point x intuitively represents the instantaneous rate of change of the function, moving through x with a direction ...
A hypothesis is a conjecture based on knowledge obtained while seeking answers to the question. Hypotheses can be very specific or broad but must be falsifiable , implying that it is possible to identify a possible outcome of an experiment or observation that conflicts with predictions deduced from the hypothesis; otherwise, the hypothesis ...
In population genetics, directional selection is a type of natural selection in which one extreme phenotype is favored over both the other extreme and moderate phenotypes. This genetic selection causes the allele frequency to shift toward the chosen extreme over time as allele ratios change from generation to generation.
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