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The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).
A separation process is a method that converts a mixture or a solution of chemical substances into two or more distinct product mixtures, [1] a scientific process of separating two or more substances in order to obtain purity. At least one product mixture from the separation is enriched in one or more of the source mixture's constituents.
Electrolysis refers to the breakdown of substances using an electric current. This removes impurities in a substance that an electric current is run through; Sublimation is the process of changing of any substance (usually on heating) from a solid to a gas (or from gas to a solid) without passing through liquid phase. In terms of purification ...
An ideal mixture is any in which the arithmetic mean (with respect to mole fraction) of the two pure substances is the same as that of the final mixture. Among other important thermodynamic simplifications, this means that enthalpy of mixing is zero: Δ H m i x , i d e a l = 0 {\displaystyle \Delta H_{mix,ideal}=0} .
While the term chemical substance is a precise technical term that is synonymous with chemical for chemists, the word chemical is used in general usage to refer to both (pure) chemical substances and mixtures (often called compounds), [14] and especially when produced or purified in a laboratory or an industrial process.
Some mixtures form azeotropes, where the mixture boils at a lower temperature than either component. In this example, a mixture of 96% ethanol and 4% water boils at 78.2 °C (172.8 °F); the mixture is more volatile than pure ethanol. For this reason, ethanol cannot be completely purified by direct fractional distillation of ethanol–water ...
[8] [9] Mixtures differ from chemical compounds in the following ways: The substances in a mixture can be separated using physical methods such as filtration, freezing, and distillation. There is little or no energy change when a mixture forms (see Enthalpy of mixing). The substances in a mixture keep their separate properties.
Thermodynamic data is usually presented as a table or chart of function values for one mole of a substance (or in the case of the steam tables, one kg). A thermodynamic datafile is a set of equation parameters from which the numerical data values can be calculated.