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Dimethyl oxalate can be converted into ethylene glycol in high yields (94.7%) [10] [11] The methanol formed is recycled in the process of oxidative carbonylation. [12] Other plants with a total annual capacity of more than 1 million tons of ethylene glycol per year are planned. Decarbonylation gives dimethyl carbonate. [13]
Synthesis of acrylic acid using "Reppe chemistry"; a metal catalyst is required. The carbomethoxylation of ethylene to give methyl propionate: C 2 H 4 + CO + MeOH → MeO 2 CC 2 H 5. Methyl propionate ester is a precursor to methyl methacrylate. [10] Hydroesterification is like hydrocarboxylation, but it uses alcohols in place of water. [11]
Oxidative carbonylation is a class of reactions that use carbon monoxide in combination with an oxidant to generate esters and carbonate esters.These transformations utilize transition metal complexes as homogeneous catalysts. [1]
Oxalate (systematic IUPAC name: ethanedioate) is an anion with the chemical formula C 2 O 2− 4. This dianion is colorless. It occurs naturally, including in some foods. It forms a variety of salts, for example sodium oxalate (Na 2 C 2 O 4), and several esters such as dimethyl oxalate ((CH 3) 2 C 2 O 4). It is a conjugate base of oxalic acid.
The oxidative carbonylation of methanol to dimethyl oxalate provides a promising approach to the production of C 1-based ethylene glycol. [11] Dimethyl oxalate can be converted into ethylene glycol in high yields (94.7%) [12] by hydrogenation with a copper catalyst: [13]
Transition metal oxalate complexes are coordination complexes with oxalate (C 2 O 4 2−) ligands. Some are useful commercially, but the topic has attracted regular scholarly scrutiny. Oxalate (C 2 O 4 2-) is a kind of dicarboxylate ligand. [1] As a small, symmetrical dinegative ion, oxalate commonly forms five-membered MO 2 C 2 chelate rings.
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Magnesium oxalate is an organic compound comprising a magnesium cation with a 2+ charge bonded to an oxalate anion. It has the chemical formula MgC 2 O 4 . Magnesium oxalate is a white solid that comes in two forms: an anhydrous form and a dihydrate form where two water molecules are complexed with the structure.