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Chloroform, [10] or trichloromethane (often abbreviated as TCM), is an organochloride with the formula C H Cl 3 and a common solvent.It is a volatile, colorless, sweet-smelling, dense liquid produced on a large scale as a precursor to refrigerants and PTFE. [11]
However, the presence of chlorine in an organic compound does not ensure toxicity. Some organochlorides are considered safe enough for consumption in foods and medicines. For example, peas and broad beans contain the natural chlorinated plant hormone 4-chloroindole-3-acetic acid (4-Cl-IAA); [ 16 ] [ 17 ] and the sweetener sucralose (Splenda) is ...
Many kinds of seaweed produce chloroform, and fungi are believed to produce chloroform in soil. [ 3 ] Most of the haloforms — specifically, chloroform ( CHCl 3 ), bromoform ( CHBr 3 ), and iodoform ( CHI 3 ) — are easy to prepare through the haloform reaction , although this method does not lend itself to bulk syntheses.
Structure and properties Index of refraction, n D: 1.4459 at 19 °C Abbe number? Dielectric constant, ε r: 4.8069 ε 0 at 20 °C : Bond strength? Bond length [1]: C-Cl 1.75 Å
Phenol is often used in combination with chloroform. [4] Adding an equal volume of chloroform and phenol ensures a distinct separation between the aqueous and organic phases. Chloroform and phenol are miscible and create a denser solution than phenol alone, aiding the separation of the organic and aqueous layers. This addition of chloroform is ...
Deuterated chloroform is a general purpose NMR solvent, as it is not very chemically reactive and unlikely to exchange its deuterium with its solute, [9] and its low boiling point allows for easy sample recovery. It, however, it is incompatible with strongly basic, nucleophilic, or reducing analytes, including many organometallic compounds.
This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
In chemistry, the haloform reaction (also referred to as the Lieben haloform reaction) is a chemical reaction in which a haloform (CHX 3, where X is a halogen) is produced by the exhaustive halogenation of an acetyl group (R−C(=O)CH 3, where R can be either a hydrogen atom, an alkyl or an aryl group), in the presence of a base.