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  2. Reaction rate constant - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate_constant

    where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here ⁠ ⁠ is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...

  3. Mayo–Lewis equation - Wikipedia

    en.wikipedia.org/wiki/Mayo–Lewis_equation

    Where P is a proportionality constant, Q is the measure of reactivity of monomer via resonance stabilization, and e is the measure of polarity of monomer (molecule or radical) via the effect of functional groups on vinyl groups. Using these definitions, and can be found by the ratio of the terms. An advantage of this system is that reactivity ...

  4. Law of definite proportions - Wikipedia

    en.wikipedia.org/wiki/Law_of_definite_proportions

    The law of definite proportion was given by Joseph Proust in 1797. [2]I shall conclude by deducing from these experiments the principle I have established at the commencement of this memoir, viz. that iron like many other metals is subject to the law of nature which presides at every true combination, that is to say, that it unites with two constant proportions of oxygen.

  5. Proportionality (mathematics) - Wikipedia

    en.wikipedia.org/wiki/Proportionality_(mathematics)

    Given such a constant k, the proportionality relation ∝ with proportionality constant k between two sets A and B is the equivalence relation defined by {(,): =}. A direct proportionality can also be viewed as a linear equation in two variables with a y-intercept of 0 and a slope of k > 0, which corresponds to linear growth.

  6. Law of mass action - Wikipedia

    en.wikipedia.org/wiki/Law_of_mass_action

    Two chemists generally expressed the composition of a mixture in terms of numerical values relating the amount of the product to describe the equilibrium state. Cato Maximilian Guldberg and Peter Waage , building on Claude Louis Berthollet 's ideas [ 4 ] [ 5 ] about reversible chemical reactions , proposed the law of mass action in 1864.

  7. Gas laws - Wikipedia

    en.wikipedia.org/wiki/Gas_laws

    where P is the pressure, V is volume, n is the number of moles, R is the universal gas constant and T is the absolute temperature. The proportionality constant, now named R, is the universal gas constant with a value of 8.3144598 (kPa∙L)/(mol∙K). An equivalent formulation of this law is: =

  8. Gay-Lussac's law - Wikipedia

    en.wikipedia.org/wiki/Gay-Lussac's_law

    For air, he found a relative expansion ΔV/V = 37.50% and obtained a value of α = 37.50%/100 °C = 1/266.66 °C which indicated that the value of absolute zero was approximately 266.66 °C below 0 °C. [12] The value of the rate of expansion α is approximately the same for all gases and this is also sometimes referred to as Gay-Lussac's Law.

  9. List of mathematical constants - Wikipedia

    en.wikipedia.org/wiki/List_of_mathematical_constants

    A mathematical constant is a key number whose value is fixed by an unambiguous definition, often referred to by a symbol (e.g., an alphabet letter), or by mathematicians' names to facilitate using it across multiple mathematical problems. [1] For example, the constant π may be defined as the ratio of the length of a circle's circumference to ...