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Sulfuric acid is a colorless oily liquid, and has a vapor pressure of <0.001 mmHg at 25 °C and 1 mmHg at 145.8 °C, [16] and 98% sulfuric acid has a vapor pressure of <1 mmHg at 40 °C. [17] In the solid state, sulfuric acid is a molecular solid that forms monoclinic crystals with nearly trigonal lattice
In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist.
A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. [1] Many examples can be found in metallurgy , geology , and solid-state chemistry .
Concentrated sulfuric acid is a strong dehydrating agent that can strip available water molecules and water components from sugar and organic tissue. [ 141 ] The burning of coal and/or petroleum by industry and power plants generates sulfur dioxide (SO 2 ) that reacts with atmospheric water and oxygen to produce sulfurous acid (H 2 SO 3 ). [ 142 ]
The hydrogensulfate ion (HSO − 4), also called the bisulfate ion, is the conjugate base of sulfuric acid (H 2 SO 4). [59] [b] Sulfuric acid is classified as a strong acid; in aqueous solutions it ionizes completely to form hydronium (H 3 O +) and hydrogensulfate (HSO − 4) ions.
Hygroscopic substances include cellulose fibers (such as cotton and paper), sugar, caramel, honey, glycerol, ethanol, wood, methanol, sulfuric acid, many fertilizer chemicals, many salts and a wide variety of other substances. [5] If a compound dissolves in water, then it is considered to be hydrophilic. [6]
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.
An ideal mixture is any in which the arithmetic mean (with respect to mole fraction) of the two pure substances is the same as that of the final mixture. Among other important thermodynamic simplifications, this means that enthalpy of mixing is zero: Δ H m i x , i d e a l = 0 {\displaystyle \Delta H_{mix,ideal}=0} .