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The olefin feed to an alkylation unit generally originates from a FCCU and contains butene, isobutene, and possibly propene and/or amylenes. The olefin feed is also likely to contain diluents (such as propane, n-butane, and n-pentane), noncondensables (such as ethane and hydrogen) and contaminants. Diluents in principle have no effect on the ...
The Julia olefination (also known as the Julia–Lythgoe olefination) is the chemical reaction used in organic chemistry of phenyl sulfones (1) with aldehydes (or ketones) to give alkenes (olefins)(3) after alcohol functionalization and reductive elimination using sodium amalgam or SmI 2.
The reaction proceeds through generation of an acylium center. The reaction is completed by deprotonation of the arenium ion by AlCl 4 −, regenerating the AlCl 3 catalyst. However, in contrast to the truly catalytic alkylation reaction, the formed ketone is a moderate Lewis base, which forms a complex with the strong Lewis acid aluminum ...
Formerly the reaction had been called "olefin disproportionation." In this reaction 2-pentene forms a rapid (a matter of seconds) chemical equilibrium with 2-butene and 3-hexene. No double bond migrations are observed; the reaction can be started with the butene and hexene as well and the reaction can be stopped by addition of methanol.
The Tsuji–Trost reaction (also called the Trost allylic alkylation or allylic alkylation) is a palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex.
This category encompasses olefination reactions, those that introduce a carbon–carbon double bond into a product molecule, creating an alkene or olefin. Pages in category "Olefination reactions" The following 21 pages are in this category, out of 21 total.
For a long time this reaction had no applications in synthetic organic chemistry. In 2002 it was used in a total synthesis of the terpene gleenol as a mild and non-basic reagent in a one-pot-protocol with an olefin metathesis step with Grubbs catalyst. [5] It is remarkable that the organometallic catalyst tolerates the inorganic reaction products.
The Peterson olefination (also called the Peterson reaction) is the chemical reaction of α-silyl carbanions (1 in diagram below) with ketones (or aldehydes) to form a β-hydroxysilane (2) which eliminates to form alkenes (3).