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Polyurethane synthesis, wherein the urethane groups −NH−(C=O)−O− link the molecular units A kitchen sponge made of polyurethane foam . Polyurethane (/ ˌ p ɒ l i ˈ jʊər ə ˌ θ eɪ n,-j ʊəˈr ɛ θ eɪ n /; [1] often abbreviated PUR and PU) refers to a class of polymers composed of organic units joined by carbamate (urethane) links.
Polyurethane dispersion, or PUD, is understood to be a polyurethane polymer resin dispersed in water, rather than a solvent, although some cosolvent may be used.Its manufacture involves the synthesis of polyurethanes having carboxylic acid functionality or nonionic hydrophiles like PEG (polyethylene glycol) incorporated into, or pendant from, the polymer backbone. [1]
Moisture cured polyurethane–urea coatings have been made by reacting 1,2,3-triazole rich polyether polyols with HMDI at NCO/OH eq. ratio of 1.2 to obtain isocyanate-terminated polyurethane prepolymers. The prepolymers were cured under atmospheric moisture to make polyurethane–urea free films. [5]
Left: individual linear polymer chains Right: Polymer chains which have been cross linked to give a rigid 3D thermoset polymer. In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening ("curing") a soft solid or viscous liquid prepolymer (). [1]
Dip coating have been utilized for example in the fabrication of bioceramic nanoparticles, biosensors, implants and hybrid coatings. For example, dip coating has been used to establish a simple yet fast nonthermal coating method to immobilize hydroxyapatite and TiO 2 nanoparticles on polymethyl methacrylate. [4]
An assortment of polyurethane foam products for cushioning and insulation. Polyurethane foam is a solid polymeric foam based on polyurethane chemistry. As a specialist synthetic material with highly diverse applications, polyurethane foams are primarily used for thermal insulation and as a cushioning material in mattresses, upholstered furniture or as seating in vehicles.
Thermoplastic polyurethane (TPU) refers to polyurethane polymers which exhibit thermoplasticity; that is, they become pliable when heated and harden when cooled.This is in contrast to most polyurethanes, which are thermosets that harden irreversibly.
Memory foam consists mainly of polyurethane with additional chemicals that increase its viscosity and density. It is often referred to as "viscoelastic" polyurethane foam, or low-resilience polyurethane foam . The foam bubbles or 'cells' are open, effectively creating a matrix through which air can move.