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An R F value will always be in the range 0 to 1; if the substance moves, it can only move in the direction of the solvent flow, and cannot move faster than the solvent. For example, if particular substance in an unknown mixture travels 2.5 cm and the solvent front travels 5.0 cm, the retardation factor would be 0.50.
The response factor can be expressed on a molar, volume or mass [1] basis. Where the true amount of sample and standard are equal: = where A is the signal (e.g. peak area) and the subscript i indicates the sample and the subscript st indicates the standard. [2]
Radio frequency (RF) is the oscillation rate of an alternating electric current or voltage or of a magnetic, electric or electromagnetic field or mechanical system in the frequency [1] range from around 20 kHz to around 300 GHz.
For instance, dichloromethane has a value of ε r of 9.08 (20 °C) and is rather poorly soluble in water (13 g/L or 9.8 mL/L at 20 °C); at the same time, tetrahydrofuran has its ε r = 7.52 at 22 °C, but it is completely miscible with water.
Effective radiated power (ERP), synonymous with equivalent radiated power, is an IEEE standardized definition of directional radio frequency (RF) power, such as that emitted by a radio transmitter.
They are the smallest difference between sorted RF values, or product of such differences. Another function is the multispot response function (MRF) as developed by De Spiegeleer et al.{Analytical Chemistry (1987):59(1),62-64} It is based also of differences product. This function always lies between 0 and 1.
Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such. This is especially problematic for francium, which by relativistic calculations can be shown to be less electronegative than caesium, but for which the only value (0.7) in the literature predates these ...
The following table gives some similar examples of points which are plotted on the Z Smith chart. For each, the reflection coefficient is given in polar form together with the corresponding normalised impedance in rectangular form. The conversion may be read directly from the Smith chart or by substitution into the equation.