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The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H 2 O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH −.
In chemistry, molecular autoionization (or self-ionization) is a chemical reaction between molecules of the same substance to produce ions. If a pure liquid partially dissociates into ions, it is said to be self-ionizing. [1]: 163 In most cases the oxidation number on all atoms in such a reaction remains unchanged. Such autoionization can be ...
For example, water undergoes autoprotolysis in the self-ionization of water reaction. 2 H 2 O ⇌ OH − + H 3 O + For example, ammonia in its purest form may undergo autoprotolysis: 2 NH 3 ⇌ NH − 2 + NH + 4. Another example is acetic acid: 2 CH 3 COOH ⇌ CH 3 COO − + CH 3 COOH + 2
Water is amphoteric, meaning that it can exhibit properties of an acid or a base, depending on the pH of the solution that it is in; it readily produces both H + and OH − ions. [c] Related to its amphoteric character, it undergoes self-ionization. The product of the activities, or approximately, the concentrations of H + and OH −
These states of neutral neon lie beyond the first ionization energy because it takes more energy to excite a 2s electron than to remove a 2p electron. When autoionization occurs, the np → 2s de-excitation provides the energy needed to remove one 2p electron and form the Ne + ground state. Other resonances are attributed to two-electron ...
The self-ionization constant of water, K w, is thus just a special case of an acid dissociation constant. A logarithmic form analogous to pK a may also be defined
Electrolysis of pure water requires excess energy in the form of overpotential to overcome various activation barriers. Without the excess energy, electrolysis occurs slowly or not at all. This is in part due to the limited self-ionization of water. Pure water has an electrical conductivity about one hundred thousandth that of seawater. [8] [9 ...
The water molecule is amphoteric in aqueous solution. It can either gain a proton to form a hydronium ion H 3 O +, or else lose a proton to form a hydroxide ion OH −. [5] Another possibility is the molecular autoionization reaction between two water molecules, in which one water molecule acts as an acid and another as a base.
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