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The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H 2 O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH −.
In chemistry, molecular autoionization (or self-ionization) is a chemical reaction between molecules of the same substance to produce ions. If a pure liquid partially dissociates into ions, it is said to be self-ionizing. [1]: 163 In most cases the oxidation number on all atoms in such a reaction remains unchanged. Such autoionization can be ...
Water is amphoteric, meaning that it can exhibit properties of an acid or a base, depending on the pH of the solution that it is in; it readily produces both H + and OH − ions. [c] Related to its amphoteric character, it undergoes self-ionization. The product of the activities, or approximately, the concentrations of H + and OH −
Autoionization is a process by which an atom or a molecule in an excited state spontaneously emits one of the outer-shell electrons, thus going from a state with charge Z to a state with charge Z + 1, for example from an electrically neutral state to a singly ionized state. [1]
For example, water undergoes autoprotolysis in the self-ionization of water reaction. 2 H 2 O ⇌ OH − + H 3 O + For example, ammonia in its purest form may undergo autoprotolysis: 2 NH 3 ⇌ NH − 2 + NH + 4. Another example is acetic acid: 2 CH 3 COOH ⇌ CH 3 COO − + CH 3 COOH + 2
The self-ionization constant of water, K w, is thus just a special case of an acid dissociation constant. ... This process, known as homoconjugation, ...
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