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Heating a suspension of vanadium pentoxide and phosphoric acid gives VOPO 4 •2H 2 O, isolated as a bright yellow solid. [4] According to X-ray crystallography, the V(V) centers are octahedral, with long, weak bonds to aquo ligands. [5] Reduction of this compound with alcohols gives the vanadium(IV) phosphates.
From left: [V(H 2 O) 6] 2+ (lilac), [V(H 2 O) 6] 3+ (green), [VO(H 2 O) 5] 2+ (blue) and [VO(H 2 O) 5] 3+ (yellow).. Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements, niobium and tantalum, are somewhat more limited to ...
In chemistry, a phosphide is a compound containing the P 3− ion or its equivalent. Many different phosphides are known, with widely differing structures. [ 1 ] Most commonly encountered on the binary phosphides, i.e. those materials consisting only of phosphorus and a less electronegative element.
A reported silicon phosphide is Si 12 P 5 (no practical applications), [89] [90] formed by annealing an amorphous Si-P alloy. The arsenic–silicon phase diagram measured at 40 Bar has two phases: SiAs and SiAs 2. [91] The antimony–silicon system comprises a single eutectic close to the melting point of Sb. [92] The bismuth system is a ...
Vanadium forms oxides in the +2, +3, +4 and +5 oxidation states, forming vanadium(II) oxide (VO), vanadium(III) oxide (V 2 O 3), vanadium(IV) oxide (VO 2) and vanadium(V) oxide (V 2 O 5). Vanadium(V) oxide or vanadium pentoxide is the most common, being precursor to most alloys and compounds of vanadium, and is also a widely used industrial ...
Vanadium(V) compounds (1 C, 12 P) Vanadyl compounds (12 P) Pages in category "Vanadium compounds" The following 9 pages are in this category, out of 9 total.
Vanadium(V) oxide (vanadia) is the inorganic compound with the formula V 2 O 5. Commonly known as vanadium pentoxide, it is a dark yellow solid, although when freshly precipitated from aqueous solution, its colour is deep orange. Because of its high oxidation state, it is both an amphoteric oxide and an oxidizing agent.
Vanadium(II) compounds are reducing agents, and vanadium(V) compounds are oxidizing agents. Vanadium(IV) compounds often exist as vanadyl derivatives, which contain the VO 2+ center. [23] Ammonium vanadate(V) (NH 4 VO 3) can be successively reduced with elemental zinc to obtain the different colors of vanadium in these four oxidation states.