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Enantiotopic groups are identical and indistinguishable except in chiral environments. For instance, the CH 2 hydrogens in ethanol (CH 3 CH 2 OH) are normally enantiotopic, but can be made different (diastereotopic) if combined with a chiral center, for instance by conversion to an ester of a chiral carboxylic acid such as lactic acid, or if coordinated to a chiral metal center, or if ...
Immunofluorescence staining pattern of sp100 antibodies. Nuclear dots can be seen in the nucleus of the cells. Produced using serum from a patient with primary biliary cirrhosis on HEp-20-10 cells with a FITC conjugate. These, or similar, bodies have been found increased in the presence of lymphoid cancers [25] [26] and SLE (lupus). [27]
Even though they share the same molar weight, glucose is more stable than galactose. This difference in stability causes galactose to be absorbed slightly faster than glucose in human body. [4] [5] Diastereoselectivity is the preference for the formation of one or more than one diastereomer over the other in an organic reaction.
An example of a proton pump that is not electrogenic, is the proton/potassium pump of the gastric mucosa which catalyzes a balanced exchange of protons and potassium ions. [citation needed] The combined transmembrane gradient of protons and charges created by proton pumps is called an electrochemical gradient.
The main idea of the Independent Particle approach is that a nucleon moves inside a certain potential well (which keeps it bound to the nucleus) independently from the other nucleons. This amounts to replacing an N-body problem (N particles interacting) by N single-body problems. This essential simplification of the problem is the cornerstone ...
Symmetrical norbornanes and similarly rigid compounds (e.g. 7-oxabicyclo[2.2.1]heptane) also show complex signals for the ethylene fragments, made more complicated by additional splitting by the bridgehead protons. Reich gives several additional examples of magnetic inequivalence in acyclic and cyclic systems containing H 2 C-CH 2 fragments. [3]
Examples include carbon-14, nitrogen-15, and oxygen-16 in the table above. Isobars are nuclides with the same number of nucleons (i.e. mass number) but different numbers of protons and neutrons. Isobars neighbor each other diagonally from lower-left to upper-right. Examples include carbon-14, nitrogen-14, and oxygen-14 in the table above.
Donnan equilibrium across a cell membrane (schematic). The Gibbs–Donnan effect (also known as the Donnan's effect, Donnan law, Donnan equilibrium, or Gibbs–Donnan equilibrium) is a name for the behaviour of charged particles near a semi-permeable membrane that sometimes fail to distribute evenly across the two sides of the membrane. [1]