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Crystals can be classified in three ways: lattice systems, crystal systems and crystal families. The various classifications are often confused: in particular the trigonal crystal system is often confused with the rhombohedral lattice system, and the term "crystal system" is sometimes used to mean "lattice system" or "crystal family".
The trigonal crystal system consists of the 5 point groups that have a single three-fold rotation axis, which includes space groups 143 to 167. These 5 point groups have 7 corresponding space groups (denoted by R) assigned to the rhombohedral lattice system and 18 corresponding space groups (denoted by P) assigned to the hexagonal lattice system.
It can be used to define the rhombohedral lattice system, a honeycomb with rhombohedral cells. A rhombohedron has two opposite apices at which all face angles are equal; a prolate rhombohedron has this common angle acute, and an oblate rhombohedron has an obtuse angle at these vertices.
In monoclinic, trigonal, tetragonal, and hexagonal systems there is one unique axis (sometimes called the principal axis) which has higher rotational symmetry than the other two axes. The basal plane is the plane perpendicular to the principal axis in these crystal systems.
Rhombohedral: R 3 m (No. 166) 105 (rh.) 315 (hex.) Partly due to its complexity, whether this structure is the ground state of Boron has not been fully settled. α-As: A7: Rhombohedral: R 3 m (No. 166) 2 (rh.) 6 (hex.) in grey metallic form, each As atom has 3 neighbours in the same sheet at 251.7pm; 3 in adjacent sheet at 312.0 pm. [18]
If the crystal system is trigonal, then the lattice system is hexagonal unless the space group is one of the seven in the rhombohedral lattice system consisting of the 7 trigonal space groups in the table above whose name begins with R. (The term rhombohedral system is also sometimes used as an alternative name for the whole trigonal system.)
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In geometry, a trigonal trapezohedron is a polyhedron with six congruent quadrilateral faces, which may be scalene or rhomboid. [1] [2] The variety with rhombus-shaped faces faces is a rhombohedron. [3] [4] An alternative name for the same shape is the trigonal deltohedron. [5]