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The methylchlorosilanes react with water to produce hydrogen chloride, giving siloxanes. In the case of trimethylsilyl chloride, the hydrolyzed product is hexamethyldisiloxane: 2 ((CH 3) 3 SiCl + H 2 O → [(CH 3) 3 Si] 2 O + 2 HCl. The analogous reaction of dimethyldichlorosilane gives siloxane polymers or rings: n (CH 3) 2 SiCl 2 + n H 2 O ...
Trichlorosilane is a reagent in the conversion of benzoic acids to toluene derivatives. In the first step of a two-pot reaction, the carboxylic acid is first converted to the trichlosilylbenzyl compound. In the second step, the benzylic silyl derivative is converted to the toluene derivative with base. [7]
TMSCl is reactive toward nucleophiles, resulting in the replacement of the chloride. In a characteristic reaction of TMSCl, the nucleophile is water, resulting in hydrolysis to give the hexamethyldisiloxane: + + The related reaction of trimethylsilyl chloride with alcohols can be exploited to produce anhydrous solutions of hydrochloric acid in alcohols, which find use in the mild synthesis of ...
Trichlorosilane is produced commercially by the reaction of hydrogen chloride with silicon: Si + 3 HCl → HSiCl 3 + H 2. Many alkoxy hydrosilanes are generated by alcoholysis of trichlorosilane. One example is triethoxysilane: HSiCl 3 + 3 EtOH → HSi(OEt) 3 + 3 HCl. Organohydrosilanes can be prepared by partial hydrosilation of silane itself:
Triethylamine is commonly used in the production of anionic Polyurethane dispersions (resins dispersed in water rather than solvents) as a neutralizing agent. Triethylamine is used to give salts of various carboxylic acid-containing pesticides, e.g. Triclopyr and 2,4-dichlorophenoxyacetic acid. [citation needed]
Methyltrichlorosilane vapor reacts with water on surfaces to give a thin layer of methylpolysiloxane, which changes the contact angle of the surface to water. This effect arises because of the oriented layer of methyl groups, making a water-repellent film. [ 4 ]
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The reaction also produces stoichiometric quantities of alkoxide base, which can catalyze the competing Dieckmann condensation. [4] Rühlmann's 's technique traps the alkoxide and the acyloin with trimethylchlorosilane for considerably improved yields. [12] The disilyl diether can then be cloven with acidified water or methanol. Rühlmann-method