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Hydrogen fluoride, a weak acid in aqueous solution that is normally not thought to have any appreciable Brønsted basicity at all, is in fact the strongest Brønsted base in the mixture, protonating to H 2 F + in the same way water protonates to H 3 O + in aqueous acid. It is the fluoronium ion that accounts for fluoroantimonic acid's extreme ...
Acetic acid is said to be a differentiating solvent for the three acids, while water is not. [6]: 217 An important example of a solvent which is more basic than water is dimethyl sulfoxide, DMSO, (CH 3) 2 SO. A compound which is a weak acid in water may become a strong acid in DMSO. Acetic acid is an example of such a substance.
Nitric acid, with a pK value of around −1.7, behaves as a strong acid in aqueous solutions with a pH greater than 1. [23] At lower pH values it behaves as a weak acid. pK a values for strong acids have been estimated by theoretical means. [24] For example, the pK a value of aqueous HCl has been estimated as −9.3.
Carborane acids H(CXB 11 Y 5 Z 6) (X, Y, Z = H, Alk, F, Cl, Br, CF 3) are a class of superacids, [1] some of which are estimated to be at least one million times stronger than 100% pure sulfuric acid in terms of their Hammett acidity function values (H 0 ≤ –18) and possess computed pK a values well below –20, establishing them as some of the strongest known Brønsted acids.
pKa (Strongest Acidic) 9.76 ChemAxon: pKa (Strongest Basic) 2.97 ChemAxon: Physiological Charge 0 ChemAxon: Hydrogen Acceptor Count 4 ChemAxon: Hydrogen Donor Count 2 ChemAxon: Polar Surface Area 101.73 Å2 ChemAxon: Rotatable Bond Count 4 ChemAxon: Refractivity 46.01 m3·mol-1 ChemAxon: Polarizability 17.89 Å3 ChemAxon: Number of Rings 1 ...
A strong superacid of this kind is fluoroantimonic acid. Another group of superacids, the carborane acid group, contains some of the strongest known acids. Finally, when treated with anhydrous acid, zeolites [ citation needed ] (microporous aluminosilicate minerals) will contain superacidic sites within their pores.
Although hydrofluoric acid is regarded as a weak acid, it is very corrosive, even attacking glass when hydrated. [20] Dilute solutions are weakly acidic with an acid ionization constant K a = 6.6 × 10 −4 (or pK a = 3.18), [10] in contrast to corresponding solutions of the other hydrogen halides, which are strong acids (pK a < 0).
Trifluoroacetic acid is a strong acid. [12] TFA is harmful when inhaled, causes severe skin burns and is toxic for aquatic organisms even at low concentrations. Skin burns are severe, heal poorly and can be necrotic. Vapour fumes have an LC 50 of 10.01 mg/L, tested on rats over 4 hours.