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Gas to liquids (GTL) is a refinery process to convert natural gas or other gaseous hydrocarbons into longer-chain hydrocarbons, such as gasoline or diesel fuel. Methane -rich gases are converted into liquid synthetic fuels .
Methanol is a promising energy carrier because, as a liquid, it is easier to store than hydrogen and natural gas. Its energy density is, however, lower than methane, per kg. Its combustion energy density is 15.6 MJ/L , whereas that of ethanol is 24 and gasoline is 33 MJ/L.
Methanol may be made from fossil fuels or renewable resources, in particular natural gas and coal, or biomass respectively. In the case of the latter, it can be synthesized from CO 2 (carbon dioxide) and hydrogen. [3] The vast majority of methanol produced globally is currently made with gas and coal. [4]
The STG+ process uses standard catalysts similar to those used in other gas to liquids technologies, specifically in methanol to gasoline processes. Methanol to gasoline processes favor molecular size- and shape-selective zeolite catalysts, [ 2 ] and the STG+ process also utilizes commercially available shape-selective catalysts, such as ZSM-5 .
Methanol can be produced from a variety of sources including fossil fuels (natural gas, coal, oil shale, tar sands, etc.) as well as agricultural products and municipal waste, wood and varied biomass. It can also be made from chemical recycling of carbon dioxide. Nobel prize laureate George A. Olah advocated a methanol economy. [1] [2] [3] [4]
Indirect conversion broadly refers to a process in which biomass, coal, or natural gas is converted to a mix of hydrogen and carbon monoxide known as syngas either through gasification or steam methane reforming, and that syngas is processed into a liquid transportation fuel using one of a number of different conversion techniques depending on ...
Methanol is the lightest and simplest alcohol, produced from the natural gas component methane. Its application is limited primarily due to its toxicity (similar to gasoline), but also due to its high corrosivity and miscibility with water. Small amounts are used in some types of gasoline to increase the octane rating. Methanol-based fuels are ...
Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, [1] in various ratios. The gas often contains some carbon dioxide and methane . It is principally used for producing ammonia or methanol .