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In thermodynamics, the enthalpy of mixing (also heat of mixing and excess enthalpy) is the enthalpy liberated or absorbed from a substance upon mixing. [1] When a substance or compound is combined with any other substance or compound, the enthalpy of mixing is the consequence of the new interactions between the two substances or compounds. [1]
The enthalpy of mixing is zero [2] as is the volume change on mixing by definition; the closer to zero the enthalpy of mixing is, the more "ideal" the behavior of the solution becomes. The vapor pressures of the solvent and solute obey Raoult's law and Henry's law , respectively, [ 3 ] and the activity coefficient (which measures deviation from ...
Lattice enthalpy - is defined as the energy required to separate one mole of an ionic compound into separated gaseous ions to an infinite distance apart (meaning no force of attraction). Enthalpy of mixing - is defined as the enthalpy change upon mixing of two (non-reacting) chemical substances.
The pure component's molar volume and molar enthalpy are equal to the corresponding partial molar quantities because there is no volume or internal energy change on mixing for an ideal solution. The molar volume of a mixture can be found from the sum of the excess volumes of the components of a mixture:
In contrast to ideal solutions, regular solutions do possess a non-zero enthalpy of mixing, due to the W term. If the unlike interactions are more unfavorable than the like ones, we get competition between an entropy of mixing term that produces a minimum in the Gibbs free energy at x 1 = 0.5 and the enthalpy term that has a maximum there.
The Gibbs free energy change = determines whether mixing at constant (absolute) temperature and pressure is a spontaneous process.This quantity combines two physical effects—the enthalpy of mixing, which is a measure of the energy change, and the entropy of mixing considered here.
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The enthalpy of solution is most often expressed in kJ/mol at constant temperature. The energy change can be regarded as being made up of three parts: the endothermic breaking of bonds within the solute and within the solvent, and the formation of attractions between the solute and the solvent. An ideal solution has a null enthalpy of mixing.