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In organic chemistry, alkylidene is a general term for divalent functional groups of the form R 2 C=, where each R is an alkane or hydrogen. [1] They can be considered the functional group corresponding to mono- or disubstituted divalent carbenes (known as alkylidenes), [2] or as the result of removing two hydrogen atoms from the same carbon atom in an alkane.
The branching in 2-ethyl-1-butanol makes it harder to crystallize due to packing disruption, which results in a very low freezing point. Esters of 2-ethyl-1-butanol are similarly effected and it therefore finds application as a feedstock in the production of plasticizers and lubricants, where its presence helps reduce viscosity and lower freezing points.
There are a wide range of applications for linear alpha olefins. The lower carbon numbers, 1-butene, 1-hexene and 1-octene are overwhelmingly used as comonomer in production of polyethylene. High-density polyethylene and linear low-density polyethylene use approximately 2-4% and 8-10% of comonomers, respectively.
2-methylprop-1-ene In the chemical structures above, the small blue numbers in the structure images are the numbering of the atoms in the main backbone chain of the molecules. Other organic compounds have the formula C 4 H 8 , namely cyclobutane and methylcyclopropane , but are not alkenes and do not fall under the name butene .
For example, of the isomers of butene, the two methyl groups of (Z)-but-2-ene (a.k.a. cis-2-butene) appear on the same side of the double bond, and in (E)-but-2-ene (a.k.a. trans-2-butene) the methyl groups appear on opposite sides. These two isomers of butene have distinct properties.
1-Butene (IUPAC name: But-1-ene, also known as 1-butylene) is the organic compound with the formula CH 3 CH 2 CH=CH 2. It is a colorless gas. But-1-ene is an alkene easily condensed to give a colorless liquid. It is classified as a linear alpha-olefin (terminal alkene). [2] It is one of the isomers of butene (butylene). It is a precursor to ...
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In ETP, ethylene is dimerized to 1-butene, which is isomerized to 2-butenes. The 2-butenes are then subjected to metathesis with ethylene. Rhenium- and molybdenum-containing heterogeneous catalysis are used. Nowadays, only the "reverse" reaction is practiced, i.e., the conversion of ethylene and 2-butene to propylene: [2]