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A cyclopropyl group is a chemical structure derived from cyclopropane; it is typically produced in a cyclopropanation reaction. The group has an empirical formula of C 3 H 5 and chemical bonds from each of the three carbons to both of the other two.
From left to right: the two isomeric groups propyl and 1-methylethyl (iPr or isopropyl), and the non-isomeric cyclopropyl group. In organic chemistry, a propyl group is a three-carbon alkyl substituent with chemical formula −CH 2 CH 2 CH 3 for the linear form.
Most cyclopropanes are not prepared from the parent cyclopropane, which is somewhat inert. Cyclopropyl groups are often prepared by cyclization of 1,3-difunctional alkanes. An example of the former, cyclopropyl cyanide is prepared by the reaction of 4-chlorobutyronitrile with a strong base. [1]
A cycloalkyl group is derived from a cycloalkane by removal of a hydrogen atom from a ring and has the general formula −C n H 2n−1. [2] Typically an alkyl is a part of a larger molecule. In structural formulae, the symbol R is used to designate a generic (unspecified) alkyl group. The smallest alkyl group is methyl, with the formula −CH 3 ...
Examples include the formation of cyclopropyl cyanide [18] and cyclopropylacetylene [19] This mechanism also forms the basis of the Favorskii rearrangement. A related process is the cyclisation of 1,3-dibromopropane via a Wurtz coupling. This was used for the first synthesis of cyclopropane by August Freund in 1881.
Some examples include: meth- (1 carbon) eth- (2 carbons) prop- (3 carbons) but- (4 carbons) pent- (5 carbons) hex- (6 carbons) Alkyl group prefixes: These prefixes are used to name alkyl groups (chains of carbon atoms) that are attached to another molecule. They are formed by adding the suffix "-yl" to the hydrocarbon prefix.
The phosphate 1 contains a chiral group with a hydrogen and a deuterium substituent. The stannyl group is replaced by lithium to intermediate 2 which undergoes a phosphate–phosphorane rearrangement to phosphorane 3 which on reaction with acetic acid gives alcohol 4. Once again in the range of −78 °C to 0 °C the chirality is preserved in ...
The abstraction of a β-proton from the alkyl fragment may form an aldehyde and an alkene. Norrish type I reaction. The synthetic utility of this reaction type is limited, for instance it often is a side reaction in the Paternò–Büchi reaction. One organic synthesis based on this reaction is that of bicyclohexylidene. [7]