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tert-Butylbenzene is an organic compound classified as an aromatic hydrocarbon. Its structure consists of a benzene ring substituted with a tert -butyl group . It is a flammable colorless liquid which is nearly insoluble in water but miscible with organic solvents.
tert-Butyl alcohol is the simplest tertiary alcohol, with a formula of (CH 3) 3 COH (sometimes represented as t-BuOH). Its isomers are 1-butanol, isobutanol, and butan-2-ol. tert-Butyl alcohol is a colorless solid, which melts near room temperature and has a camphor-like odor. It is miscible with water, ethanol and diethyl ether.
Firstly, 2,4-dimethyl-6-tert-butylphenol is reacted with formaldehyde and HCl (Blanc reaction) to generate a chloromethyl group in the less hindered meta position. This intermediate then reacts with cyanuric acid to give the desired product.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate is a high molecular weight additive, with low volatility. It is well suited to stabilising polyolefins against degradation caused by long term heat aging. [1] It is an approved food contact material in the US. [2]
Pages in category "Tert-butyl compounds" The following 200 pages are in this category, out of approximately 203 total. This list may not reflect recent changes .
5.5 tert-Butyl. 6 Hexane. Toggle Hexane subsection. 6.1 Pentamethyl. ... 2,4-Dimethyl-3-(1-methylethyl)hexane; 2,5-Dimethyl-3-(1-methylethyl)hexane; Pentane. Hexamethyl
Budipine can be prepared from the 1-tert-butyl-4-piperidone [1465-76-5] directly by treatment with benzene in the presence triflic acid. [12] This method of synthesis enables a 99% yield of product. Thieme Synthesis: [ 13 ]