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In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
A coefficient is a constant coefficient when it is a constant function. For avoiding confusion, in this context a coefficient that is not attached to unknown functions or their derivatives is generally called a constant term rather than a constant coefficient.
If the degree of p is greater than the degree of q, then the limit is positive or negative infinity depending on the signs of the leading coefficients; If the degree of p and q are equal, the limit is the leading coefficient of p divided by the leading coefficient of q; If the degree of p is less than the degree of q, the limit is 0.
For example, they are used to form polynomial equations, which encode a wide range of problems, from elementary word problems to complicated scientific problems; they are used to define polynomial functions, which appear in settings ranging from basic chemistry and physics to economics and social science; and they are used in calculus and ...
the work function in physics; the energy required by a photon to remove an electron from the surface of a metal; magnetic flux or electric flux; the cumulative distribution function of the normal distribution in statistics; phenyl functional group in organic chemistry (pseudoelement symbol)
where A is the pre-exponential factor for the reaction, R is the universal gas constant, T is the absolute temperature (usually in kelvins), and k is the reaction rate coefficient. Even without knowing A, E a can be evaluated from the variation in reaction rate coefficients as a function of temperature (within the validity of the Arrhenius ...
Partition coefficient (K D) - The ratio of concentrations of a compound in two phases of a mixture of two immiscible solvents at equilibrium. Hall coefficient (electrical physics) - Relates a magnetic field applied to an element to the voltage created, the amount of current and the element thickness. It is a characteristic of the material from ...