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Chlorine (17 Cl) has 25 isotopes, ranging from 28 Cl to 52 Cl, and two isomers, 34m Cl and 38m Cl. There are two stable isotopes, 35 Cl (75.8%) and 37 Cl (24.2%), giving chlorine a standard atomic weight of 35.45. The longest-lived radioactive isotope is 36 Cl, which has a half-life of 301,000 years. All other isotopes have half-lives under 1 ...
Isotope peaks within a spectrum can help in structure elucidation. Compounds containing halogens (especially chlorine and bromine) can produce very distinct isotope peaks. The mass spectrum of methylbromide has two prominent peaks of equal intensity at m/z 94 (M) and 96 (M+2) and then two more at 79 and 81 belonging to the bromine fragment.
Chlorine-37 (37 Cl), is one of the stable isotopes of chlorine, the other being chlorine-35 (35 Cl). Its nucleus contains 17 protons and 20 neutrons for a total of 37 nucleons. Chlorine-37 accounts for 24.23% of natural chlorine, chlorine-35 accounting for 75.77%, giving chlorine atoms in bulk an apparent atomic weight of 35.45(1) g/mol. [1]
Trace amounts of radioactive 36 Cl exist in the environment, in a ratio of about (7–10) × 10 −13 to 1 with respect to the stable chlorine isotopes. [2] [3] This 36 Cl/Cl ratio is sometimes abbreviated as R 36 Cl. This corresponds to a concentration of approximately 1 Bq/(kg Cl). 36 Cl is produced in the atmosphere by spallation of 36 Ar by ...
Ion mobility spectrometry-mass spectrometry (IMS/MS or IMMS) is a technique where ions are first separated by drift time through some neutral gas under an applied electrical potential gradient before being introduced into a mass spectrometer. [43] Drift time is a measure of the collisional cross section relative to the charge of the ion.
Isotope-ratio mass spectrometry (IRMS) is a specialization of mass spectrometry, in which mass spectrometric methods are used to measure the relative abundance of isotopes in a given sample. [1] [2] This technique has two different applications in the earth and environmental sciences.
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The most stable chlorine radioisotope is 36 Cl. The primary decay mode of isotopes lighter than 35 Cl is electron capture to isotopes of sulfur; that of isotopes heavier than 37 Cl is beta decay to isotopes of argon; and 36 Cl may decay by either mode to stable 36 S or 36 Ar. [42] 36 Cl occurs in trace quantities in nature as a cosmogenic ...