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Measurements of primary productivity in the ocean can be made using this ratio. The concentration of oxygen dissolved in seawater varies according to biological processes (photosynthesis and respiration) as well as physical processes (air-sea gas exchange, temperature and pressure changes, lateral mixing and vertical diffusion).
Marine chemistry, also known as ocean chemistry or chemical oceanography, is the study of the chemical composition and processes of the world’s oceans, including the interactions between seawater, the atmosphere, the seafloor, and marine organisms. [2]
The solubility of gas obeys Henry's law, that is, the amount of a dissolved gas in a liquid is proportional to its partial pressure. Therefore, placing a solution under reduced pressure makes the dissolved gas less soluble. Sonication and stirring under reduced pressure can usually enhance the efficiency.
Water is the medium of the oceans, the medium which carries all the substances and elements involved in the marine biogeochemical cycles. Water as found in nature almost always includes dissolved substances, so water has been described as the "universal solvent" for its ability to dissolve so many substances.
However, for aqueous solutions, the Henry's law solubility constant for many species goes through a minimum. For most permanent gases, the minimum is below 120 °C. Often, the smaller the gas molecule (and the lower the gas solubility in water), the lower the temperature of the maximum of the Henry's law constant.
The solubility pump is driven by the coincidence of two processes in the ocean : The solubility of carbon dioxide is a strong inverse function of seawater temperature (i.e. solubility is greater in cooler water) The thermohaline circulation is driven by the formation of deep water at high latitudes where seawater is usually cooler and denser
In the ocean by volume, the most abundant gases dissolved in seawater are carbon dioxide (including bicarbonate and carbonate ions, 14 mL/L on average), nitrogen (9 mL/L), and oxygen (5 mL/L) at equilibrium at 24 °C (75 °F) [122] [123] [124] All gases are more soluble – more easily dissolved – in colder water than in warmer water. For ...
The amount of gas dissolved in a liquid is described by Henry's Law, which indicates that when the pressure of a gas in contact with a liquid is decreased, the amount of that gas dissolved in the liquid will also decrease proportionately. On ascent from a dive, inert gas comes out of solution in a process called "outgassing" or