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The faster reactions involve the transfer of an electron from BPh − (BPh − is oxidized to BPh) to the electron acceptor quinone (Q A), and the transfer of an electron to P960 + (P960 + is reduced to P960) from a heme in the cytochrome subunit above the reaction center. The high-energy electron that resides on the tightly bound quinone ...
Chemical energy is the energy that can be released when chemical substances undergo a transformation through a chemical reaction. Breaking and making chemical bonds involves energy release or uptake, often as heat that may be either absorbed by or evolved from the chemical system.
In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...
These reactions have a free reaction enthalpy ΔG 0 which is independent of the reorganization energy and determined by the different redox potentials of the iron and cobalt couple. Consequently, the quadratic Marcus equation holds also for the inner sphere reorganization energy, including the prediction of an inverted region.
A is the pre-exponential factor or Arrhenius factor or frequency factor. Arrhenius originally considered A to be a temperature-independent constant for each chemical reaction. [6] However more recent treatments include some temperature dependence – see § Modified Arrhenius equation below. E a is the molar activation energy for the reaction,
The energy of these rays is sometimes sufficient to start photonuclear reactions resulting in emitted neutrons. One such reaction, 14 7 N (γ,n) 13 7 N, is the only natural process other than those induced by cosmic rays in which 13 7 N is produced on Earth. The unstable isotopes remaining from the reaction may subsequently emit positrons by β ...
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In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...