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p-Dimethylaminobenzophenone is related to Michler's ketone, but with only one amine. [5] Auramine O, a dye, is a salt of the iminium cation [(CH 3) 2 NC 6 H 4] 2 CNH 2 +.Michler's thione, [(CH 3) 2 NC 6 H 4] 2 CS, is prepared by treatment of Michler's ketone with hydrogen sulfide in the presence of acid or sulfideing auramine O. [6] Hydride reduction of Michler's ketone gives 4,4'-bis ...
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4-Bromophenylacetic acid may be prepared by the addition of a bromine atom to phenylacetic acid through electrophilic aromatic substitution.It was first prepared in the laboratory by treatment of phenylacetic acid with bromine and mercuric oxide; a mixture of the 2- and 4- isomers is made, and the 4- isomer is isolated by fractional crystallization.
The acidity of the methylene group in diphenylmethane is due to the weakness of the (C 6 H 5) 2 CH–H bond, which has a bond dissociation energy of 82 kcal mol −1 (340 kJ mol −1). [5] This is well below the published bond dissociation energies for comparable C–H bonds in propane , where BDE((CH 3 ) 2 CH–H)=98.6 kcal mol −1 , and ...
In organic chemistry, brosyl (or para-bromophenylsulfonyl) group is a functional group with the chemical formula BrC 6 H 4 SO 2 and structure Br−C 6 H 4 −SO 2 −R. This group is usually introduced using the compound brosyl chloride, BrC 6 H 4 SO 2 Cl, which forms sulfonyl esters and amides of p-bromophenylsulfonic acid. The term brosylate ...
4-Bromoaniline is a compound where an aniline molecule is substituted with a bromine atom on the para position. Commercially available, this compound may be used as a building block, e.g. in the preparation of monobrominated biphenyl via the Gomberg-Bachmann reaction .
Phenylacetylindoles: Any compound containing a 3-phenylacetylindole structure with substitution at the nitrogen atom of the indole ring by an alkyl, haloalkyl, alkenyl, cycloalkylmethyl, cycloalkylethyl,1-(N-methyl-2-piperidinyl)methyl, or 2-(4-morpholinyl)ethyl group whether or not further substituted in the indole ring to any extent and whether or not substituted in the phenyl ring to any ...
Bromoform was discovered in 1832 by Löwig who distilled a mixture of bromal and potassium hydroxide, as analogous to preparation of chloroform from chloral. [5]Bromoform can be prepared by the haloform reaction using acetone and sodium hypobromite, by the electrolysis of potassium bromide in ethanol, or by treating chloroform with aluminium bromide.