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They range from those of water at very low concentrations approaching 0% HCl to values for fuming hydrochloric acid at over 40% HCl. [ 31 ] [ 32 ] [ 33 ] Hydrochloric acid as the binary (two-component) mixture of HCl and H 2 O has a constant-boiling azeotrope at 20.2% HCl and 108.6 °C (381.8 K; 227.5 °F).
Aqua regia (/ ˈ r eɪ ɡ i ə, ˈ r iː dʒ i ə /; from Latin, "regal water" or "royal water") is a mixture of nitric acid and hydrochloric acid, optimally in a molar ratio of 1:3. [ b ] Aqua regia is a fuming liquid.
An example of a negative azeotrope is hydrochloric acid at a concentration of 20.2% and 79.8% water (by mass). Hydrogen chloride boils at −85 °C and water at 100 °C, but the azeotrope boils at 110 °C, which is higher than either of its constituents. The maximum boiling point of any hydrochloric acid solution is 110 °C. Other examples:
For example H 3 O + CuCl 2 − forms in concentrated hydrochloric acid. [15] Chloride is displaced by CN − and S 2 O 3 2−. [12] Solutions of CuCl in HCl absorb carbon monoxide to form colourless complexes such as the chloride-bridged dimer [CuCl(CO)] 2. The same hydrochloric acid solutions also react with acetylene gas to form [CuCl(C 2 H 2)].
The third stable eutectic has 18.4% (mass) of NaOH. It solidifies at about −28.7 °C as a mixture of water ice and the heptahydrate NaOH·7H 2 O. [18] [22] When solutions with less than 18.4% NaOH are cooled, water ice crystallizes first, leaving the NaOH in solution. [18] The α form of the tetrahydrate has density 1.33 g/cm 3.
Fe 2 O 3 + 6 HCl + 9 H 2 O → 2 FeCl 3 (H 2 O) 6. In complementary route, iron metal can be oxidized by hydrochloric acid followed by chlorination: [10] Fe + 2 HCl → FeCl 2 + H 2 FeCl 2 + 0.5 Cl 2 + 6 H 2 O → FeCl 3 (H 2 O) 6. A number of variables apply to these processes, including the oxidation of iron by ferric chloride and the ...
It can be created by neutralising hydrochloric acid with calcium hydroxide. Calcium chloride is commonly encountered as a hydrated solid with generic formula CaCl 2 ·nH 2 O, where n = 0, 1, 2, 4, and 6. These compounds are mainly used for de-icing and dust control. Because the anhydrous salt is hygroscopic and deliquescent, it is used as a ...