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In the "black ash" process, celesite is roasted with coke at 1100–1300 °C to form strontium sulfide. [3] The sulfate is reduced, leaving the sulfide: SrSO 4 + 2 C → SrS + 2 CO 2. A mixture of strontium sulfide with either carbon dioxide gas or sodium carbonate then leads to formation of a precipitate of strontium carbonate. [4] [3]
Solubility tables; Substance Formula 0 °C 10 °C 15 °C 20 °C 30 °C 40 °C 50 °C 60 °C ... (C 6 H 5) 4: 47: Sodium thiosulfate: Na 2 S 2 O 3: 71.5: 73: 77.6: 90 ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The ideal formula of strontianite is SrCO 3, with molar mass 147.63 g, [4] but calcium (Ca) can substitute for up to 27% of the strontium (Sr) cations, and barium (Ba) up to 3.3%. [ 2 ] The mineral was named in 1791 for the locality, Strontian , Argyllshire, Scotland, where the element strontium had been discovered the previous year. [ 2 ]
Solubility constants are used to describe saturated solutions of ionic compounds of relatively low solubility (see solubility equilibrium). The solubility constant is a special case of an equilibrium constant. Since it is a product of ion concentrations in equilibrium, it is also known as the solubility product. It describes the balance between ...
The effect of the particle size on solubility constant can be quantified as follows: = + where *K A is the solubility constant for the solute particles with the molar surface area A, *K A→0 is the solubility constant for substance with molar surface area tending to zero (i.e., when the particles are large), γ is the surface tension ...
8.04 (9.4 °C) Silver iodide: 15.82 Silver thiocyanate: 11.94 Strontium carbonate: 8.80 ... Solubility products of metal sulfides (data page) References
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