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In the "black ash" process, celesite is roasted with coke at 1100–1300 °C to form strontium sulfide. [3] The sulfate is reduced, leaving the sulfide: SrSO 4 + 2 C → SrS + 2 CO 2. A mixture of strontium sulfide with either carbon dioxide gas or sodium carbonate then leads to formation of a precipitate of strontium carbonate. [4] [3]
Solubility tables; Substance Formula 0 °C 10 °C 15 °C 20 °C 30 °C 40 °C 50 °C ... NH 4 C 7 H 5 O 2: 19.6: 21.3: 83 Ammonium bicarbonate: NH 4 HCO 3: 11.9: 16.1 ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Solubility constants are used to describe saturated solutions of ionic compounds of relatively low solubility (see solubility equilibrium). The solubility constant is a special case of an equilibrium constant. Since it is a product of ion concentrations in equilibrium, it is also known as the solubility product. It describes the balance between ...
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[2] [3] [4] They were first described by physical chemist Kenneth Pitzer. [5] The parameters of the Pitzer equations are linear combinations of parameters, of a virial expansion of the excess Gibbs free energy, which characterise interactions amongst ions and solvent. The derivation is thermodynamically rigorous at a given level of expansion.
The effect of the particle size on solubility constant can be quantified as follows: = + where *K A is the solubility constant for the solute particles with the molar surface area A, *K A→0 is the solubility constant for substance with molar surface area tending to zero (i.e., when the particles are large), γ is the surface tension ...
8.04 (9.4 °C) Silver iodide: 15.82 Silver thiocyanate: 11.94 Strontium carbonate: 8.80 ... Solubility products of metal sulfides (data page) References