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The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
The saturation with respect to water cannot be measured much below –50 °C, so manufacturers should use one of the following expressions for calculating saturation vapour pressure relative to water at the lowest temperatures – Wexler (1976, 1977), [1] [2] reported by Flatau et al. (1992)., [3] Hyland and Wexler (1983) or Sonntag (1994 ...
where temperature T is in degrees Celsius (°C) and saturation vapor pressure P is in kilopascals (kPa). According to Monteith and Unsworth, "Values of saturation vapour pressure from Tetens' formula are within 1 Pa of exact values up to 35 °C." Murray (1967) provides Tetens' equation for temperatures below 0 °C: [3]
The path or series of states through which a system passes from an initial equilibrium state to a final equilibrium state [1] and can be viewed graphically on a pressure-volume (P-V), pressure-temperature (P-T), and temperature-entropy (T-s) diagrams. [2] There are an infinite number of possible paths from an initial point to an end point in a ...
A saturation dome uses the projection of a P–v–T diagram (pressure, specific volume, and temperature) onto the P–v plane. The points that create the left-hand side of the dome represent the saturated liquid states, while the points on the right-hand side represent the saturated vapor states (commonly referred to as the “dry” region).
This is the case, for example, for liquid water at atmospheric pressure and room temperature. In a plot that compares pressure and specific volume (commonly called a p-v diagram), compressed fluid is the state to the left of the saturation curve. Conditions that cause a fluid to be compressed include:
P s (T) is the saturation vapor pressure in hPa; exp(x) is the exponential function; T is the air temperature in degrees Celsius; Buck (1981) also lists enhancement factors for a temperature range of −80 to 50 °C (−112 to 122 °F) at pressures of 1,000 mb, 500 mb, and 250 mb. These coefficients are listed in the table below.
The Antoine equation is = +. where p is the vapor pressure, T is temperature (in °C or in K according to the value of C) and A, B and C are component-specific constants.. The simplified form with C set to zero: