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In solid-state physics, metal-induced gap states are electron states that exist near the surface of a semiconductor due to the presence of a metal on the surface. They have energies that fall within the semiconductor's bandgap thus are forbidden in the bulk of the semiconductor.
The nature of these metal-induced gap states and their occupation by electrons tends to pin the center of the band gap to the Fermi level, an effect known as Fermi level pinning. Thus the heights of the Schottky barriers in metal–semiconductor contacts often show little dependence on the value of the semiconductor or metal work functions, in ...
For binuclear reductive elimination, the oxidation state of each metal decreases by one, while the d-electron count of each metal increases by one. This type of reactivity is generally seen with first row metals, which prefer a one-unit change in oxidation state, but has been observed in both second and third row metals.
If there is a state at the Fermi level (ϵ = μ), then this state will have a 50% chance of being occupied. The distribution is plotted in the left figure. The closer f is to 1, the higher chance this state is occupied. The closer f is to 0, the higher chance this state is empty.
The pseudogap is then produced by incoherent fluctuations of the pairing field. [10] The pseudogap is a normal state precursor of the superconducting gap due to local, dynamic pairing correlations. [11] This point of view is supported by a quantitative approach of the attractive pairing model to specific heat experiments. [12] 2.
Liquid metal embrittlement (also known as LME and liquid metal induced embrittlement) is a phenomenon of practical importance, where certain ductile metals experience drastic loss in tensile ductility or undergo brittle fracture when exposed to specific liquid metals.
This effect is attributed to the antibacterial behavior of metal ions, which are absorbed by bacteria upon contact and damage their cell membranes. [1] In modern times, the effect was observed by Carl Nägeli, although he did not identify the cause. [2] Brass doorknobs, brass handrails, and silverware all exhibit this effect to an extent.
Metasomatism (from the Greek μετά metá "change" and σῶμα sôma "body") is the chemical alteration of a rock by hydrothermal and other fluids. [1] It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. [2]