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2 I − + 2 Fe 3+ → I 2 + 2 Fe 2+ (E 0 = +0.23 V) Ferric iodide, a black solid, is not stable in ordinary conditions, but can be prepared through the reaction of iron pentacarbonyl with iodine and carbon monoxide in the presence of hexane and light at the temperature of −20 °C, with oxygen and water excluded. [ 68 ]
Iron(II) chloride tetrahydrate, FeCl 2 ·4H 2 O. In chemistry, iron(II) refers to the element iron in its +2 oxidation state. The adjective ferrous or the prefix ferro-is often used to specify such compounds, as in ferrous chloride for iron(II) chloride (FeCl 2). The adjective ferric is used instead for iron(III) salts, containing the cation Fe 3+.
Iron meteorites consist overwhelmingly of nickel-iron alloys. The metal taken from these meteorites is known as meteoric iron and was one of the earliest sources of usable iron available to humans. Iron was extracted from iron–nickel alloys, which comprise about 6% of all meteorites that fall on the Earth.
Iron fertilization is the intentional introduction of iron-containing compounds (like iron sulfate) to iron-poor areas of the ocean surface to stimulate phytoplankton production. This is intended to enhance biological productivity and/or accelerate carbon dioxide (CO 2 ) sequestration from the atmosphere.
Iron–sulfur clusters are molecular ensembles of iron and sulfide. They are most often discussed in the context of the biological role for iron–sulfur proteins , which are pervasive. [ 2 ] Many Fe–S clusters are known in the area of organometallic chemistry and as precursors to synthetic analogues of the biological clusters.
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