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  2. Relations between heat capacities - Wikipedia

    en.wikipedia.org/wiki/Relations_between_heat...

    The heat capacity depends on how the external variables of the system are changed when the heat is supplied. If the only external variable of the system is the volume, then we can write: d S = ( ∂ S ∂ T ) V d T + ( ∂ S ∂ V ) T d V {\displaystyle dS=\left({\frac {\partial S}{\partial T}}\right)_{V}dT+\left({\frac {\partial S}{\partial V ...

  3. Maxwell relations - Wikipedia

    en.wikipedia.org/wiki/Maxwell_relations

    is pressure, temperature, volume, entropy, coefficient of thermal expansion, compressibility, heat capacity at constant volume, heat capacity at constant pressure. Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials .

  4. Heat capacity ratio - Wikipedia

    en.wikipedia.org/wiki/Heat_capacity_ratio

    In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure (C P) to heat capacity at constant volume (C V).

  5. Bridgman's thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Bridgman's_thermodynamic...

    The first derivatives of the internal energy with respect to its (extensive) natural variables S and V yields the intensive parameters of the system - The pressure P and the temperature T . For a simple system in which the particle numbers are constant, the second derivatives of the thermodynamic potentials can all be expressed in terms of only ...

  6. Thermal equation of state of solids - Wikipedia

    en.wikipedia.org/wiki/Thermal_equation_of_state...

    In physics, the thermal equation of state is a mathematical expression of pressure P, temperature T, and, volume V.The thermal equation of state for ideal gases is the ideal gas law, expressed as PV=nRT (where R is the gas constant and n the amount of substance), while the thermal equation of state for solids is expressed as:

  7. Isobaric process - Wikipedia

    en.wikipedia.org/wiki/Isobaric_process

    For a thermally perfect diatomic gas, the molar specific heat capacity at constant pressure (c p) is 7 / 2 R or 29.1006 J mol −1 deg −1. The molar heat capacity at constant volume (c v) is 5 / 2 R or 20.7862 J mol −1 deg −1. The ratio of the two heat capacities is 1.4. [4] The heat Q required to bring the gas from 300 to 600 K is

  8. Thermal pressure - Wikipedia

    en.wikipedia.org/wiki/Thermal_Pressure

    Figure 1: Thermal pressure as a function of temperature normalized to A of the few compounds commonly used in the study of Geophysics. [3]The thermal pressure coefficient can be considered as a fundamental property; it is closely related to various properties such as internal pressure, sonic velocity, the entropy of melting, isothermal compressibility, isobaric expansibility, phase transition ...

  9. Heat capacity - Wikipedia

    en.wikipedia.org/wiki/Heat_capacity

    The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is an extensive property. The corresponding intensive property is the specific heat capacity, found by dividing the heat capacity of an object by its mass. Dividing the heat capacity by the amount of substance in moles yields its molar heat capacity.