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In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
An atom (or ion) whose oxidation number increases in a redox reaction is said to be oxidized (and is called a reducing agent). It is accomplished by loss of one or more electrons. The atom whose oxidation number decreases gains (receives) one or more electrons and is said to be reduced. This relation can be remembered by the following mnemonics.
The number indicates the degree of oxidation of each element caused by molecular bonding. In ionic compounds, the oxidation numbers are the same as the element's ionic charge. Thus for KCl, potassium is assigned +1 and chlorine is assigned -1. [4] The complete set of rules for assigning oxidation numbers are discussed in the following sections.
As the number of oxygen atoms bound to chlorine increases, the chlorine's oxidation number becomes more positive. This gives rise to the following common pattern: first, the -ate ion is considered to be the base name; adding a per-prefix adds an oxygen, while changing the -ate suffix to -ite will reduce the oxygens by one, and keeping the suffix -ite and adding the prefix hypo-reduces the ...
Nitrogen trioxide or nitrate radical is an oxide of nitrogen with formula NO 3, consisting of three oxygen atoms covalently bound to a nitrogen atom. This highly unstable blue compound has not been isolated in pure form, but can be generated and observed as a short-lived component of gas, liquid, or solid systems.
Bismuth(III) nitrate is a salt composed of bismuth in its cationic +3 oxidation state and nitrate anions. The most common solid form is the pentahydrate. [3] It is used in the synthesis of other bismuth compounds. [4] It is available commercially. It is the only nitrate salt formed by a group 15 element, indicative of bismuth's metallic nature. [5]
Sodium nitrate is the chemical compound with the formula Na N O 3.This alkali metal nitrate salt is also known as Chile saltpeter (large deposits of which were historically mined in Chile) [4] [5] to distinguish it from ordinary saltpeter, potassium nitrate.
The compound is prepared by oxidation of cobalt(II) salts in the presence of sodium nitrite: [3] 4 [Co(H 2 O) 6 ](NO 3 ) 2 + O 2 + 24 NaNO 2 → 4 Na 3 [Co(NO 2 ) 6 ] + 8 NaNO 3 + 4 NaOH + 22 H 2 O Application for analysis of potassium