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An electrolytic cell is an electrochemical cell that utilizes an external source of electrical energy to force a chemical reaction that would otherwise not occur. [ 1 ] : 64, 89 [ 2 ] : GL7 The external energy source is a voltage applied between the cell's two electrodes ; an anode (positively charged electrode) and a cathode (negatively ...
An electrolytic cell is an electrochemical cell in which applied electrical energy drives a non-spontaneous redox reaction. [5] A modern electrolytic cell consisting of two half reactions, two electrodes, a salt bridge, voltmeter, and a battery. They are often used to decompose chemical compounds, in a process called electrolysis.
Electrolytic cell producing chlorine (Cl 2) and sodium hydroxide (NaOH) from a solution of common salt. For example, in a solution of ordinary table salt (sodium chloride, NaCl) in water, the cathode reaction will be 2 H 2 O + 2e − → 2 OH − + H 2. and hydrogen gas will bubble up; the anode reaction is 2 NaCl → 2 Na + + Cl 2 + 2e −
A galvanic cell consists of two half-cells, such that the electrode of one half-cell is composed of metal A, and the electrode of the other half-cell is composed of metal B; the redox reactions for the two separate half-cells are thus: A n + + n e − ⇌ A B m + + m e − ⇌ B. The overall balanced reaction is:
The electrode at which oxidation (a loss of electrons) takes place. For fuel cells and other galvanic cells, the anode is the negative terminal; for electrolytic cells (where electrolysis occurs), the anode is the positive terminal. [57] Aqueous solution [58] Of, relating to, or resembling water Made from, with, or by water. Catalyst
Proton exchange membrane (PEM) electrolysis is the electrolysis of water in a cell equipped with a solid polymer electrolyte (SPE) [3] that is responsible for the conduction of protons, separation of product gases, and electrical insulation of the electrodes.
The Downs cell uses a carbon anode and an iron cathode.The electrolyte is sodium chloride that has been heated to the liquid state. Although solid sodium chloride is a poor conductor of electricity, when molten the sodium and chloride ions are mobilized, which become charge carriers and allow conduction of electric current.
Castner–Kellner apparatus. The apparatus shown is divided into two types of cells separated by slate walls. The first type, shown on the right and left of the diagram, uses an electrolyte of sodium chloride solution, a graphite anode (A), and a mercury cathode (M).