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2,6-Dimethylnaphthalene is mainly used for the preparation of 2,6-naphthalenedicarboxylic acid by oxidation of 2,6-dimethylnaphthalene in the liquid phase. 2,6-Naphthalenedicarboxylic acid is a monomer for the production of high-performance polymers, in particular poly (ethylene-2,6-naphthalene dicarboxylate) or shorter polyethylene naphthalate (PEN). [4]
It was first prepared by Robert Evert and Victor Merz in 1876 by hydrolysis of 2,6-dicyanonaphthalene. [2] [3] 1,8-Naphthalenedicarboxylic acid can be isomerized to 2,6-naphthalenedicarboxylic acid via the intermediacy of the dipotassium dicarboxylates. [2] It is also produced by oxidation of 2,6-diisopropylnaphthalene. [4]
Syringol is the organic compound with the formula HO(CH 3 O) 2 C 6 H 3. The molecule is a phenol, with methoxy groups in the flanking (2 and 6) positions. It is the symmetrically dimethylated derivative of pyrogallol. It is a colorless solid, although typical samples are brown owing to air-oxidized impurities.
C 6 H 5 MgBr + CS 2 → C 6 H 5 CS 2 MgBr C 6 H 5 CS 2 MgBr + HCl → C 6 H 5 CS 2 H + MgBrCl. It is about 100x more acidic than benzoic acid. Its conjugate base, dithiobenzoate, undergoes S-alkylation to give dithiocarboxylate esters. [2] Similarly, dithiobenzoate reacts with "soft" metal salts to give complexes, e.g. Fe(S 2 CC 6 H 5) 3 and Ni ...
DMCM (methyl 6,7-dimethoxy-4-ethyl-β-carboline-3-carboxylate) is a drug from the β-carboline family that induces anxiety and convulsions by acting as a negative allosteric modulator of GABA A receptors — functionally opposite to benzodiazepines and related drugs which are positive allosteric modulators — and is used in scientific research for these properties to test new anxiolytic and ...
The diamine can also be produced by reaction of the 1,8-diol with ammonia at high temperatures. The peri-naphthalene 1-amino-naphthalene-8-sulfonic acid is a precursor to other peri-naphthalenes. It is prepared by nitration of naphthalene-1-sulfonic acid followed by reduction. Diazotization followed by loss of N 2 gives the naphthosulfone. This ...
Synthesis of symmetric and unsymmetric NDIs. NTCDI is redox-active, forming stable radical anions at –1.10 V vs. Fc/Fc + in Dichloromethane. [5] Its ability to accept electrons reflects the presence of an extended conjugated ring system and the electron withdrawing groups (carbonyl centers).
A solution of lithium naphthalenide, the lithium salt of naphthalene, in tetrahydrofuran. The alkali metal naphthalene salts are prepared by stirring the metal with naphthalene in an ethereal solvent, usually as tetrahydrofuran or dimethoxyethane. The resulting salt is dark green. [2] [3] [4] The anion is a radical, giving a strong EPR signal ...