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Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. [1]
A metamorphic reaction is a chemical reaction that takes place during the geological process of metamorphism wherein one assemblage of minerals is transformed into a second assemblage which is stable under the new temperature/pressure conditions resulting in the final stable state of the observed metamorphic rock. [1]
Metasomatism (from the Greek μετά metá "change" and σῶμα sôma "body") is the chemical alteration of a rock by hydrothermal and other fluids. [1] It is traditionally defined as metamorphism which involves a change in the chemical composition, excluding volatile components. [2]
This contact metamorphism results in a rock that is altered and re-crystallized by the extreme heat of the magma and/or by the addition of fluids from the magma that add chemicals to the surrounding rock (metasomatism). Any pre-existing type of rock can be modified by the processes of metamorphism. [4] [5]
The final mineralogy depends both on rock and fluid compositions, temperature, and pressure. Antigorite forms in reactions at temperatures that can exceed 600 °C (1,112 °F) during metamorphism, and it is the serpentine group mineral stable at the highest temperatures.
The metamorphic rock exposed in orogenic belts may have been metamorphosed simply by being at great depths below the Earth's surface, subjected to high temperatures and the great pressure caused by the immense weight of the rock layers above. This kind of regional metamorphism is known as burial metamorphism.
This is due to the loss of fluids (e.g. CO 2, H 2 O) from prograde metamorphism, after which there is insufficient fluid to permit reverse reaction of the mineral assemblages. [ 1 ] [ 3 ] Another reason is that the rocks are of inappropriate composition to generate all the minerals that record their complete metamorphic events. [ 1 ]
reaction with chemically reactive wall rocks, usually of reduced oxidation state, such as iron-bearing rocks, mafic or ultramafic rocks, or carbonate rocks; degassing of the hydrothermal fluid into a gas and water system, or boiling, which alters the metal carrying capacity of the solution and even destroys metal-carrying chemical complexes